Wide band gap p-type windows by CBD and SILAR methods

被引:98
作者
Sankapal, BR [1 ]
Goncalves, E [1 ]
Ennaoui, A [1 ]
Lux-Steiner, MC [1 ]
机构
[1] Hahn Meitner Inst Berlin GmbH, Dept Solar Energy Res, D-14109 Berlin, Germany
关键词
thin films; chemical methods; p-type; wide band gap;
D O I
10.1016/j.tsf.2003.11.002
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Chemical deposition methods, namely, chemical bath deposition (CBD) and successive ionic layer adsorption and reaction (SILAR) have been used to deposit wide band gap p-type CuI and CuSCN thin films at room temperature (25 degreesC) in aqueous medium. Growth of these films requires the use of Cu (I) cations as a copper ions source. This is achieved by complexing Cu (II) ions using Na2S2O3. The anion sources are either KI as iodine or KSCN as thiocyanide ions for CuI and CuSCN films, respectively. The preparative parameters are optimized with the aim to use these p-type materials as windows for solar cells. Different substrates are used, namely: glass, fluorine doped tin oxide coated glass and CuInS2 (CIS). X-ray diffraction, scanning electron microscopy, atomic force microscopy and optical absorption spectroscopy are used for structural, surface morphological and optical studies, and the results are discussed. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码:128 / 132
页数:5
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