Structure and properties of composite nanomaterials: Products of the thermal treatment of molybdenum- and iron-containing powders

被引:3
作者
Novoselova, L. Yu. [1 ]
机构
[1] Russian Acad Sci, Siberian Branch, Inst Petr Chem, Tomsk 634021, Russia
关键词
composite nanomaterials; molybdenum; molybdenum oxides; iron oxides; thermal treatment; structure; microdistortions (microstresses) of lattices; texture; sorption; carbon monoxide; CARBON NANOTUBES; PHASE-TRANSITION; WATER; NANOCOMPOSITES; NANOPARTICLES; SORBENTS; POLYSTYRENE; SURFACE;
D O I
10.1134/S0036024412110210
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Samples of composite nanomaterials obtained by the thermal treatment of mixtures of MoO3 nano-dispersed powder and ultrafine powder of Mo with precipitate from removing iron from groundwater are studied by means of X-ray diffraction and infrared spectroscopy. The structure of these samples (phase composition, average crystallite size, microdistortions (microstresses) of their crystal lattices, and certain texture parameters) are determined. It is suggested that under certain conditions, shells from the nanoparticles of Mo and/or MoO3 are formed on the surface of sediment particles, preventing the identification of iron-containing phases. Estimates are made of the sorption activity of some materials with respect to carbon monoxide (CO).
引用
收藏
页码:1689 / 1696
页数:8
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