Biocorrosion behavior of micro-arc-oxidized AZ31 magnesium alloy in different simulated dynamic physiological environments

被引:40
作者
Han, Linyuan [1 ,2 ]
Li, Xuan [3 ]
Xue, Feng [1 ,2 ]
Chu, Chenglin [1 ,2 ]
Bai, Jing [1 ,2 ]
机构
[1] Southeast Univ, Sch Mat Sci & Engn, Nanjing 211189, Jiangsu, Peoples R China
[2] Southeast Univ, Jiangsu Key Lab Adv Metall Mat, Nanjing 211189, Jiangsu, Peoples R China
[3] Nanjing Inst Technol, Sch Mat Engn, Nanjing 211189, Jiangsu, Peoples R China
基金
中国国家自然科学基金;
关键词
Magnesium alloy; Micro-arc oxidization; Flow field; Surface coating; Biocorrosion; IN-VIVO CORROSION; MG ALLOYS; DEGRADATION BEHAVIOR; RESEARCH PROGRESS; OXIDATION MAO; FLOW; MECHANISM; RESISTANCE; IMPLANTS; RATES;
D O I
10.1016/j.surfcoat.2019.01.052
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The micro-arc-oxidization (MAO) technique was used to form the protective coating on the surface of AZ31 magnesium alloy and the corrosion performance of the coated magnesium alloy in static and different dynamic flow environments with three flow rates in simulated body fluid (SBF) were systematically studied in this paper. The results suggested that the protective effect of MAO coating was relatively weakened in simulated dynamic environments than that in static solution and the corrosion rate was accelerated when the flow rate arose. It is noticed that the corrosion current density (i(corr)) of coated Mg alloy and the flow rate (v) matches the linear relationship of i(corr)(-1) similar to v(-1/2), and the relationships between log(i(corr)) and corrosion time (t) at different v were polynomial fitted based on the electrochemical results. The calculated threshold of t when the coating and products layer lost their protective effects became earlier as the v increased. The influence of the flow field on the biocorrosion behavior of MAO coated magnesium alloy and the evolution of the protective effect of the coating during the corrosion process was also discussed. Our work provides a novel theoretical reference for studying the biocorrosion performance of coated magnesium alloys for future biomedical applications.
引用
收藏
页码:240 / 248
页数:9
相关论文
共 50 条
[1]   The in vivo and in vitro corrosion of high-purity magnesium and magnesium alloys WZ21 and AZ91 [J].
Abidin, Nor Ishida Zainal ;
Rolfe, Barbara ;
Owen, Helen ;
Malisano, Julian ;
Martin, Darren ;
Hofstetter, Joelle ;
Uggowitzer, Peter J. ;
Atrens, Andrej .
CORROSION SCIENCE, 2013, 75 :354-366
[2]  
Bagotsky V.S., 2005, FUNDAMENTALS ELECTRO, P51, DOI [10.1002/047174199X.ch4, DOI 10.1002/047174199X.CH4]
[3]   Microscopic bio-corrosion evaluations of magnesium surfaces in static and dynamic conditions [J].
Bontrager, J. ;
Mahapatro, A. ;
Gomes, A. S. .
JOURNAL OF MICROSCOPY, 2014, 255 (02) :104-115
[4]  
Cao C. N., 2008, PRINCIPLES ELECTROCH, P65
[5]   Dynamic degradation behavior of MgZn alloy in circulating m-SBF [J].
Chen, Ying ;
Zhang, Shaoxiang ;
Li, Jianan ;
Song, Yang ;
Zhao, Changli ;
Zhang, Xiaonong .
MATERIALS LETTERS, 2010, 64 (18) :1996-1999
[6]   Fabrication and degradation behavior of micro-arc oxidized biomedical magnesium alloy wires [J].
Chu, C. L. ;
Han, X. ;
Bai, J. ;
Xue, F. ;
Chu, P. K. .
SURFACE & COATINGS TECHNOLOGY, 2012, 213 :307-312
[7]   Corrosion resistance of a self-healing micro-arc oxidation/polymethyltrimethoxysilane composite coating on magnesium alloy AZ31 [J].
Cui, Lan-Yue ;
Gao, Shang-Dong ;
Li, Ping-Ping ;
Zeng, Rong-Chang ;
Zhang, Fen ;
Li, Shuo-Qi ;
Han, En-Hou .
CORROSION SCIENCE, 2017, 118 :84-95
[8]   Degradation mechanism of micro-arc oxidation coatings on biodegradable Mg-Ca alloys: The influence of porosity [J].
Cui, Lan-Yue ;
Zeng, Rong-Chang ;
Guan, Shao-Kang ;
Qi, Wei-Chen ;
Zhang, Fen ;
Li, Shuo-Qi ;
Han, En-Hou .
JOURNAL OF ALLOYS AND COMPOUNDS, 2017, 695 :2464-2476
[9]  
Deng X. G., 2009, CORROSION BEHAV AZ31
[10]  
Efird K.D., 2011, Uhligs Corrosion Handbook, P203