Activator-free and one-pot C-allylation by simple palladium catalyst in water

被引：13

作者：

Shue, Yi-Jen ^{[1
]}

Yang, Shyh-Chyun ^{[1
]}

机构：

[1] Kaohsiung Med Univ, Coll Pharm, Sch Pharm, Kaohsiung 807, Taiwan

来源：

TETRAHEDRON LETTERS | 2012年 / 53卷 / 11期

关键词：

Activator-free; Allylic alcohols; Palladium; Water; Cyclic 1,3-diones; ALLYLIC SUBSTITUTION-REACTIONS; METHYLENE-COMPOUNDS; PHOSPHOLIPASE A(2); ATOM ECONOMY; ALCOHOLS; AMINATION; INHIBITORS; NUCLEOPHILES; ALKYLATIONS; COMPLEX;

D O I：

10.1016/j.tetlet.2012.01.022

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

For atom economic and green chemistry concepts, we develop a reaction that involves one-pot and one step to construct the C-C bond without the help of any activating reagents for allylic alcohols in water. The palladium-catalyzed allylation of cyclic 1,3-diones using allylic alcohols directly gave the corresponding allylated products in 8-99% yields. (C) 2012 Elsevier Ltd. All rights reserved.

引用

页码：1380 / 1384

页数：5

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