Solubility of Water in Octan-1-ol from (275 to 369) K

被引：51

作者：

Lang, Brian E. ^{[1
]}

机构：

[1] NIST, Gaithersburg, MD 20899 USA

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2012年 / 57卷 / 08期

关键词：

Titration;

D O I：

10.1021/je3001427

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The solubility of water in octan-1-ol was measured from 275.15 K to 369.15 K by coulometric Karl Fischer titration. The mass fraction solubility, s(c), at 298.15 K was found to be (48.91 +/- 0.13) mg.g(-1). Experiments indicated the existence of a pseudoequilibrium state when there was a significant difference in the temperature of the liquid and the headspace gas. The density of water-saturated octanol (WSO) was measured from 288.15 K to 318.15 K. The density at 298.15 K was determined to be (831.7 +/- 1.7) kg.m(-3) with a change in density of 0.6 kg.m(-3).K-1.

引用

页码：2221 / 2226

页数：6

共 14 条

[1]

[Anonymous], 2012, The Jackknife and Bootstrap

[2] EVALUATION OF THERMODYNAMIC FUNCTIONS FROM EQUILIBRIUM CONSTANTS [J].