Performance enhancement of biodiesel fueled SOFC using paper-structured catalyst

被引：19
作者：
Shiratori, Yusuke [1 ,2 ,3 ]
Tran Quang-Tuyen [1 ]
Sasaki, Kazunari [1 ,2 ,3 ,4 ]
机构：
[1] Kyushu Univ, Fac Engn, Nishi Ku, Fukuoka 8190395, Japan
[2] Kyushu Univ, Int Inst Carbon Neutral Energy Res WPI, Nishi Ku, Fukuoka 8190395, Japan
[3] Kyushu Univ, Next Generat Fuel Cell Res Ctr, Nishi Ku, Fukuoka 8190395, Japan
[4] Kyushu Univ, Int Res Ctr Hydrogen Energy, Nishi Ku, Fukuoka 8190395, Japan
来源：
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2013年 / 38卷 / 23期
关键词：
Solid oxide fuel cell; Biodiesel; Oleic-FAME; Paper-structured catalyst; CARBON DEPOSITION; DIRECT OXIDATION; ANODE MATERIALS; ACID; CELL; FEASIBILITY; BEHAVIOR; PFAD;
D O I：
10.1016/j.ijhydene.2013.05.128
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
In this study, performance of solid oxide fuel cell (SOFC) connected with paper-structured catalyst (PSC) was evaluated in the direct feed of wet oleic fatty acid methyl ester (oleic-FAME, C19H36O2), which is a mono-unsaturated component of practical biodiesel fuels (BDFs), in the steam to carbon ratio (S/C) range between 2.0 and 3.5, and high current density of 1 A cm(-2) (at 0.7 V) was recorded at 800 degrees C. Long term stability of oleic-FAME fueled SOFC was achieved by the incorporation of PSC into SOFC even under severe operating condition prone to coking (direct feed of unsaturated hydrocarbon with carbon number 19 and low S/C ratio of 2.0). After 100 h test, coking was not observed in both SOFC anode and PSC. Copyright (C) 2013, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码：9856 / 9866
页数：11
相关论文
共 34 条
  • [1] Mono and bifunctional pathways of CO2/CH4 reforming over Pt and Rh based catalysts
    Bitter, JH
    Seshan, K
    Lercher, JA
    [J]. JOURNAL OF CATALYSIS, 1998, 176 (01) : 93 - 101
  • [2] From Ni-YSZ to sulfur-tolerant anode materials for SOFCs: electrochemical behavior, in situ characterization, modeling, and future perspectives
    Cheng, Zhe
    Wang, Jeng-Han
    Choi, YongMan
    Yang, Lei
    Lin, M. C.
    Liu, Meilin
    [J]. ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (11) : 4380 - 4409
  • [3] Ceramic-based Anode Materials for Improved Redox Cycling of Solid Oxide Fuel Cells
    Fu, Q. X.
    Tietz, F.
    [J]. FUEL CELLS, 2008, 8 (05) : 283 - 293
  • [4] THE REACTIVITY OF OXIDES WITH WATER-VAPOR
    FUBINI, B
    BOLIS, V
    BAILES, M
    STONE, FS
    [J]. SOLID STATE IONICS, 1989, 32-3 : 258 - 272
  • [5] Capturing of bisphenol A photodecomposition intermediates by composite TiO2-zeolite sheets
    Fukahori, S
    Ichiura, H
    Kitaoka, T
    Tanaka, H
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2003, 46 (03) : 453 - 462
  • [6] Steam reforming behavior of methanol using paper-structured catalysts: Experimental and computational fluid dynamic analysis
    Fukahori, Shuji
    Koga, Hirotaka
    Kitaoka, Takuya
    Nakamura, Mitsuyoshi
    Wariishi, Hiroyuki
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2008, 33 (06) : 1661 - 1670
  • [7] Haneda T, 2010, P 9 NOV GAS CONV S L
  • [8] Internal reforming of SOFCs - Carbon deposition on fuel electrode and subsequent deterioration of cell
    Iida, Tatsuya
    Kawano, Mitsunobu
    Matsui, Toshiaki
    Kikuchi, Ryuji
    Eguchi, Koichi
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2007, 154 (02) : B234 - B241
  • [9] Direct oxidation of liquid fuels in a solid oxide fuel cell
    Kim, H
    Park, S
    Vohs, JM
    Gorte, RJ
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2001, 148 (07) : A693 - A695
  • [10] Feasibility of liquid hydrocarbon fuels for SOFC with Ni-ScSZ anode
    Kishimoto, Haruo
    Yamaji, Katsuhiko
    Horita, Teruhisa
    Xiong, Yueping
    Sakai, Natsuko
    Brito, Manuel E.
    Yokokawa, Harumi
    [J]. JOURNAL OF POWER SOURCES, 2007, 172 (01) : 67 - 71
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