Removal of caffeine from aqueous solution by green approach using Ficus Benjamina zero-valent iron/copper nanoparticles

被引:17
作者
Abdel-Aziz, Hossam Mohammed [1 ]
Farag, Rabie Saad [2 ]
Abdel-Gawad, Soha Ali [3 ]
机构
[1] Chem Ind Dev CID Co, Haram St, Giza 12553, Egypt
[2] Al Azhar Univ, Dept Chem, Fac Sci, Cairo, Egypt
[3] Cairo Univ, Dept Chem, Fac Sci, Giza, Egypt
关键词
Caffeine; bimetallic; nZVFe; Cu; Ficus Benjamina; green synthesized; linear and non-linear models; ACTIVATED CARBON; WASTE-WATER; DEGRADATION; ADSORPTION; COPPER; IRON; DYE; ANTIBACTERIAL; TEA; TRANSFORMATION;
D O I
10.1177/0263617420947495
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Green synthesis approach was successful used extract was successful in preparing bimetallic zero-valent Iron/Copper nanoparticles [FB-nZVFe/Cu]. Scanning Electron Microscope [SEM], Fourier Transform Infrared Spectroscopy [FTIR], and Dispersive X-ray Spectroscopy [EDX] showing the synthesizing of FB-nZVFe/Cu. The removal efficiency of Caffeine [5 mg L-1] reached 86% under the conditions [0.2 g L-1, 45 min, and pH 5]. The adsorption data are more appropriate by the Langmuir model [R-2 = 0.9987] with q(max) = 34.34 mg g(-1). Kinetic results showed that Caffeine uptake is following pseudo-second-order. Langmuir and pseudo-second-order are more appropriate in linear and non-linear models. Overall, FB-Fe/Cu is a committed green substance for removal Caffeine from aqueous solutions. Functional parameters affect investigated using the Linear regression analysis, we found them to account for over 98% of the variables affecting the removal procedure.
引用
收藏
页码:325 / 343
页数:19
相关论文
共 51 条
[1]  
Abdel-Aziz H.M., 2020, J SCI-ADV MATER DEV, V4, P1, DOI DOI 10.15406/OAJS.2020.04.00142
[2]   Paracetamol removal by bimetallic zero-valent Fe/Cu with benjamina leaf extract [J].
Abdel-Aziz, Hossam Mohammed ;
Farag, Rabie Saad ;
Abdel-Gawad, Soha Ali .
JOURNAL OF ENVIRONMENTAL ENGINEERING AND SCIENCE, 2020, 15 (03) :119-129
[3]   Carbamazepine Removal from Aqueous Solution by Green Synthesis Zero-Valent Iron/Cu Nanoparticles with Ficus Benjamina Leaves' Extract [J].
Abdel-Aziz, Hossam Mohammed ;
Farag, Rabie Saad ;
Abdel-Gawad, Soha Ali .
INTERNATIONAL JOURNAL OF ENVIRONMENTAL RESEARCH, 2019, 13 (05) :843-852
[4]  
Abdel-Gawad S. A., 2016, J ENV BIOTECHNOLOGY, V5, P18
[5]   Removal of Pharmaceuticals From Aqueous Medium Using Entrapped Activated Carbon in Alginate [J].
Abdel-Gawad, Soha A. ;
Abd El-Aziz, Hossam M. .
AIR SOIL AND WATER RESEARCH, 2019, 12
[6]   Removal of ethinylestradiol by adsorption process from aqueous solutions using entrapped activated carbon in alginate biopolymer: isotherm and statistical studies [J].
Abdel-Gawad, Soha A. ;
Abdel-Aziz, Hossam M. .
APPLIED WATER SCIENCE, 2019, 9 (04)
[7]   Removal of caffeine from aqueous solution by indirect electrochemical oxidation using a graphite-PVC composite electrode: A role of hypochlorite ion as an oxidising agent [J].
Al-Qaim, Fouad F. ;
Mussa, Zainab H. ;
Othman, Mohamed R. ;
Abdullah, Md P. .
JOURNAL OF HAZARDOUS MATERIALS, 2015, 300 :387-397
[8]  
Ali M. M., 2012, Pakistan Journal of Nutrition, V11, P336
[9]  
ALY AA, 2013, FOOD SCI QUALITY MAN, V22, P28
[10]   Iron, copper and silver nanoparticles: Green synthesis using green and black tea leaves extracts and evaluation of antibacterial, antifungal and aflatoxin B1 adsorption activity [J].
Asghar, Muhammad Asif ;
Zahir, Erum ;
Shahid, Syed Muhammad ;
Khan, Muhammad Naseem ;
Asghar, Muhammad Arif ;
Iqbal, Javed ;
Walker, Gavin .
LWT-FOOD SCIENCE AND TECHNOLOGY, 2018, 90 :98-107