Novel 4-(2,2,6,6-tetramethylpiperidin-4-ylamino)-1,8-naphthalimide based yellow-green emitting fluorescence sensors for transition metal ions and protons

被引：43

作者：

Bojinov, Vladimir B. ^{[1
]}

Panova, Ionka P. ^{[1
]}

机构：

[1] Univ Chem Technol & Met, Dept Organ Synth, BU-1756 Sofia, Bulgaria

来源：

DYES AND PIGMENTS | 2009年 / 80卷 / 01期

基金：

美国国家科学基金会;

关键词：

1,8-Naphthalimide; Fluorescence; Hindered amine light stabilizer (HALS); 2-(2-Hydroxyphenyl)-benzotriazole UV absorbers; Sensors; Photoinduced electron transfer (PET); PHOTOINDUCED ELECTRON-TRANSFER; PHOTOPHYSICAL PROPERTIES; 1,8-NAPHTHALIMIDE DYES; LUMINESCENT PROPERTIES; TRANSFER PET; COPOLYMERS; SOLVENT; METHYLMETHACRYLATE; CHEMOSENSOR; RECEPTORS;

D O I：

10.1016/j.dyepig.2008.05.007

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Two novel yellow-green emitting 1,8-naphthalimides, containing a 4-amino-2,2,6,6-tetramethylpiperidinyl moiety, were configured as "fluorophore-spacer-receptor" systems. The photophysical characteristics of the dyes were investigated in both DMF and water/DMF (4:1, v/v) solutions. The ability of the new compounds to detect cations was evaluated by means of the changes in their fluorescence intensity imparted by the presence of transition metal ions (Cu2+, Pb2+, Zn2+, Ni2+) and protons. The presence of metal ions and protons was found to disallow photoinduced electron transfer resulting in enhanced fluorescence intensity. The results clearly show that only Cu2+ ions and protons were effectively detected, indicating the potential of the novel compounds as highly efficient "off-on" switchers for CU2+ ions and protons. (C) 2008 Elsevier Ltd. All rights reserved.

引用

页码：61 / 66

页数：6

共 65 条

[1]

Alexiou M.S., 1990, J. Chem.Soc. Perkin Trans 2, V5, P837, DOI 10.1039/P29900000837

[2]

[Anonymous], 1987, Organic Chemistry in Colour

[3] Synthetic receptors as sensors - Preface [J].

Anslyn, EV .

TETRAHEDRON, 2004, 60 (49) :11055-11056

[4]

Balzani V, 2000, ANGEW CHEM INT EDIT, V39, P3348, DOI 10.1002/1521-3773(20001002)39:19<3348::AID-ANIE3348>3.0.CO

[5]

2-X

[6] Photochemical molecular devices [J].

Balzani, V .

PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES, 2003, 2 (05) :459-476

[7]

BISSELL RA, 1993, TOP CURR CHEM, V168, P223

[8] MOLECULAR FLUORESCENT SIGNALING WITH FLUOR SPACER RECEPTOR SYSTEMS - APPROACHES TO SENSING AND SWITCHING DEVICES VIA SUPRAMOLECULAR PHOTOPHYSICS [J].

BISSELL, RA ;

DE SILVA, AP ;

GUNARATNE, HQN ;

LYNCH, PLM ;

MAGUIRE, GEM ;

SANDANAYAKE, KRAS .

CHEMICAL SOCIETY REVIEWS, 1992, 21 (03) :187-195

[9] Synthesis and absorption properties of new yellow-green emitting benzo[de]isoquinoline-1,3-diones containing hindered amine and 2-hydroxyphenylbenzotriazole fragments [J].

Bojinov, Vladimir B. ;

Panova, Ionka P. .

DYES AND PIGMENTS, 2007, 74 (03) :551-560

[10] Side-chain electroluminescent polymers [J].

Bouche, CM ;

Berdague, P ;

Facoetti, H ;

Robin, P ;

LeBarny, P ;

Schott, M .

SYNTHETIC METALS, 1996, 81 (2-3) :191-195

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