4-phenyl-decahydro-1H-1,5-benzodiazepin-2-one as novel and effective corrosion inhibitor for carbon steel in 1 M HCl solution: A combined experimental and empirical studies

被引:24
作者
Al Garadi, W. [1 ]
Jrajri, K. [2 ]
El Faydy, M. [3 ]
Benhiba, F. [2 ,4 ]
El Ghayati, L. [1 ]
Sebbar, N. K. [1 ,5 ]
Essassi, E. M. [1 ]
Warad, I. [6 ]
Guenbour, A. [2 ]
Bellaouchou, A. [2 ]
Jama, C. [7 ]
Alsalme, A. [8 ]
Zarrouk, A. [2 ]
机构
[1] Mohammed V Univ Rabat, Fac Sci, Dept Chem, Lab Heterocycl Organ Chem, 1014, Rabat, Morocco
[2] Mohammed V Univ Rabat, Fac Sci, Lab Mat Nanotechnol & Environm, POB 1014, Rabat, Morocco
[3] Ibn Tofail Univ, Fac Sci, Dept Chem, Lab Organ Chem Inorgan Electrochem & Environm, POB 133, Kenitra 14000, Morocco
[4] Ibn Tofail Univ, Fac Sci, Lab Adv Mat & Proc Engn, POB 133, Kenitra 14000, Morocco
[5] Ibn Zohr Univ, Fac Sci, Lab Chem & Environm, Appl Bioorgan Chem Team, Agadir, Morocco
[6] An Najah Natl Univ, Dept Chem, POB 7, Nablus, Palestine
[7] Univ Lille, UMET Unite Mat & Transformat, CNRS, INRAE,Cent Lille,UMR 8207, F-59000 Lille, France
[8] King Saud Univ, Coll Sci, Chem Dept, 1145, Riyadh, Saudi Arabia
关键词
Benzodiazepine; Carbon steel corrosion; Electrochemical measurements; SEM; DFT; Molecular dynamics simulation; HYDROCHLORIC-ACID SOLUTION; MILD-STEEL; MOLECULAR-DYNAMICS; ORGANIC-COMPOUNDS; SURFACE-ANALYSIS; PHOSPHORIC-ACID; SCHIFF-BASES; MONTE-CARLO; C40E STEEL; DERIVATIVES;
D O I
10.1016/j.jics.2022.100742
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The heterocyclic system, namely 4-phenyl-decahydro-1H-1,5-benzodiazepin-2-one (POBZ) was inspected as a corrosion inhibitor of carbon steel (CS) in a 1 M HCl medium through electrochemical impedance spectroscopy (EIS), potentiodynamic polarization measurements (PDP), and scanning electron microscopy (SEM). The experimental data indicate that the inhibiting action augments with augmenting POBZ amount and reduces with augmenting temperature. The inhibiting action efficiency of 90.98% is obtained with 0.001 M at 303 K. The potentiodynamic polarization (PDP) results mentioned that the POBZ is of mixed type. The adsorption of POBZ on the CS followed Langmuir isotherm. SEM exams affirmed that the steel surface is smooth in presence of POBZ. In light of the calculations of density functional theory (DFT) and molecular dynamics simulation, the mecha-nism of POBZ inhibitory activity was addressed.
引用
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页数:14
相关论文
共 85 条
[1]   Empirical and quantum chemical studies on the corrosion inhibition performance of some novel synthesized cationic gemini surfactants on carbon steel pipelines in acid pickling processes [J].
Abd El-Lateef, Hany M. ;
Abo-Riya, Mohamed A. ;
Tantawy, Ahmed H. .
CORROSION SCIENCE, 2016, 108 :94-110
[2]   Experimental and empirical assessment of two new 8-hydroxyquinoline analogs as effective corrosion inhibitor for C22E steel in 1 M HCl [J].
About, H. ;
El Faydy, M. ;
Benhiba, F. ;
Kerroum, Y. ;
Kaichouh, G. ;
Oudda, H. ;
Guenbour, A. ;
Lakhrissi, B. ;
Warad, I ;
Zarrouk, A. .
JOURNAL OF MOLECULAR LIQUIDS, 2021, 325
[3]  
About H., 2019, Journal of Bioand Tribo-Corrosion, V5, P50
[4]   Synthesis, Crystal Structure and Computational Investigation of New 4-Phenyl-decahydro-1H-1,5-benzodiazepin-2-one as Potent Inhibitor of Mu-opioid Receptor [J].
Al Garadi, Wedad ;
El Bakri, Youness ;
Lai, Chin-Hung ;
Karthikeyan, Subramani ;
El Ghayati, Lhoussaine ;
Mague, Joel T. ;
Essassi, El Mokhtar .
CHEMISTRYSELECT, 2020, 5 (15) :4601-4607
[5]   Synthesis, characterization, and anti-corrosion properties of an 8-hydroxyquinoline derivative [J].
Alamshany, Zahra M. ;
Ganash, Aisha A. .
HELIYON, 2019, 5 (11)
[6]   Glycyrrhiza glabra leaves extract as a green corrosion inhibitor for mild steel in 1 M hydrochloric acid solution: Experimental, molecular dynamics, Monte Carlo and quantum mechanics study [J].
Alibakhshi, Eiman ;
Ramezanzadeh, Mohammad ;
Bahlakeh, Ghasem ;
Ramezanzadeh, Bahram ;
Mandavian, Moharninad ;
Motamedi, Milad .
JOURNAL OF MOLECULAR LIQUIDS, 2018, 255 :185-198
[7]   MOLECULAR-DYNAMICS SIMULATIONS AT CONSTANT PRESSURE AND-OR TEMPERATURE [J].
ANDERSEN, HC .
JOURNAL OF CHEMICAL PHYSICS, 1980, 72 (04) :2384-2393
[8]  
[Anonymous], 2016, MAT STUDIO REVISION
[9]   CHEMISTRY OF BENZODIAZEPINES [J].
ARCHER, GA ;
STERNBACH, LH .
CHEMICAL REVIEWS, 1968, 68 (06) :747-+
[10]   L-Alanine methyl ester nitrate ionic liquid: synthesis, characterization and anti-corrosive application [J].
Aslam, Ruby ;
Mobin, Mohammad ;
Huda ;
Murmu, Manilal ;
Banerjee, Priyabrata ;
Aslam, Jeenat .
JOURNAL OF MOLECULAR LIQUIDS, 2021, 334