Ionothermal synthesis of a metal-organic framework constructed by magnesium(II) and 4,4′-oxybis(benzoic acid) ligand

被引：15
作者：
Wu, Zhao-Feng [1 ]
Feng, Mei-Ling [1 ]
Hu, Bing [1 ]
Tan, Bin [1 ]
Huang, Xiao-Ying [1 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2012年 / 24卷
关键词：
Ionothermal synthesis; Magnesium; 4,4 '-Oxybis(benzoic acid); Metal-organic framework; STRUCTURAL-CHARACTERIZATION; COORDINATION POLYMERS; CRYSTAL-STRUCTURE; GUEST-EXCHANGE; TEMPERATURE; DIMENSIONALITY; ADSORPTION; NETWORK; CHAINS; UNITS;
D O I：
10.1016/j.inoche.2012.06.024
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
By using the ionic liquid 1-butyl-2,3-dimethylimidazolium bromide ([Bmmim]Br) as solvent and reactant, a magnesium(II) metal complex, namely, [Bmmim][Mg-3(oba)(3)(obaH)] (1) (obaH(2) = 4,4'-oxybis(benzoic acid)) has been synthesized ionothermally, which represents the first Mg(II)-oba metal-organic framework. Single-crystal X-ray analysis indicated that the structure of 1 featured a three-dimensionally anionic framework of [Mg-3(oba)(3)(obaH)](n)(n-). Photoluminescence measurements revealed that 1 exhibited strong emission at 387 nm ascribed to ligand-to-metal charge transfer. (c) 2012 Elsevier B.V. All rights reserved.
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收藏
页码：166 / 169
页数：4
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