Sulfur containing platinum(II) complexes with N-heterocyclic carbene ligands obtained by reactions of a hydrosulfido complex

被引：13
|
作者：
Maeda, Yuri [1 ]
Hashimoto, Hideki [2 ,3 ,4 ]
Nishioka, Takanori [1 ,3 ]
机构：
[1] Osaka City Univ, Dept Chem, Grad Sch Sci, Sumiyoshi Ku, Osaka 5588585, Japan
[2] Osaka City Univ, Dept Phys, Grad Sch Sci, Osaka 5588585, Japan
[3] Japan Sci & Technol Agcy, CREST, Kawaguchi, Saitama 3320012, Japan
[4] Osaka City Univ, OCU Adv Res Inst Nat Sci & Technol OCARINA, Osaka 5588585, Japan
来源：
DALTON TRANSACTIONS | 2012年 / 41卷 / 39期
关键词：
OLEFIN METATHESIS CATALYSTS; LIGATED S-2(2-) IONS; OXYGEN-ATOM TRANSFER; MOLECULAR-STRUCTURE; CRYSTAL-STRUCTURES; METAL-COMPLEXES; STRUCTURAL CHARACTERIZATION; RUTHENIUM COMPLEXES; NITROGEN-COMPOUNDS; BRIDGED DIIRIDIUM;
D O I：
10.1039/c2dt30597f
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A hydrosulfido platinum(II) complex with a chelated N-heterocyclic carbene (NHC) ligand was oxidised with O-2 in the presence of excess hydrogen sulfide, to give a linear tetrasulfido complex, and without hydrogen sulfide, to give a thiosulfato-bridged dinuclear complex. The hydrosulfido complex also reacted with an acetato complex containing the chelating NHC platinum unit to afford a trinuclear platinum complex with two triply bridging sulfido ligands showing an equilibrium in solution between two isomers based on the arrangement of the chelating NHC ligands.
引用
收藏
页码：12038 / 12047
页数：10
相关论文
共 50 条
  • [41] Rhenium chalcogenide clusters containing N-heterocyclic carbene ligands
    Szczepura, Lisa
    Wilson, Wade
    Huh, Daniel
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2015, 250
  • [42] On the Bonding in N-Heterocyclic Carbene Complexes of Germanium(II)
    Ruddy, Adam J.
    Rupar, Paul A.
    Bladek, Kamila J.
    Allan, Christopher J.
    Avery, Jessica C.
    Baines, Kim M.
    ORGANOMETALLICS, 2010, 29 (06) : 1362 - 1367
  • [43] Hydroamination of Unactivated Alkenes Catalyzed by Novel Platinum(II) N-Heterocyclic Carbene Complexes
    Cao, Peng
    Cabrera, Jose
    Padilla, Robin
    Serra, Daniel
    Rominger, Frank
    Limbach, Michael
    ORGANOMETALLICS, 2012, 31 (03) : 921 - 929
  • [44] Synthesis and characterization of palladacyclopentadiene complexes with N-heterocyclic carbene ligands
    Canovese, Luciano
    Santo, Claudio
    Scattolin, Thomas
    Visentin, Fabiano
    Bertolasi, Valerio
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2015, 794 : 288 - 300
  • [45] Rhenium and Technetium Tricarbonyl Complexes of N-Heterocyclic Carbene Ligands
    Chan, Chung Ying
    Pellegrini, Paul A.
    Greguric, Ivan
    Barnard, Peter J.
    INORGANIC CHEMISTRY, 2014, 53 (20) : 10862 - 10873
  • [46] Nonchelate and chelate complexes of palladium(II) with N-heterocyclic carbene ligands of amido functionality
    Liao, Chuang-Yi
    Chan, Kai-Ting
    Zeng, Jing-Yao
    Hu, Ching-Han
    Tu, Cheng-Yi
    Lee, Hon Man
    ORGANOMETALLICS, 2007, 26 (07) : 1692 - 1702
  • [47] Bridged dinucleating N-heterocyclic carbene ligands and their double helical mercury(II) complexes
    Scheele, Ulrich Juergen
    Dechert, Sebastian
    Meyer, Franc
    INORGANICA CHIMICA ACTA, 2006, 359 (15) : 4891 - 4900
  • [48] Novel mesoionic/remote N-heterocyclic carbene ligands and their ruthenium(II) aqua complexes
    Cao, Thomas
    Grotjahn, Douglas
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 253
  • [49] Chemistry of N-Heterocyclic Carbene Ligands
    Jahnke, Mareike C.
    Hahn, F. Ekkehardt
    TRANSITION METAL COMPLEXES OF NEUTRAL ETA1-CARBON LIGANDS, 2010, 30 : 95 - +
  • [50] Luminescent Complexes of Platinum, Iridium, and Coinage Metals Containing N-Heterocyclic Carbene Ligands: Design, Structural Diversity, and Photophysical Properties
    Amouri, Hani
    CHEMICAL REVIEWS, 2023, 123 (01) : 230 - 270
12345