A simple unimolecular multiplexer/demultiplexer

被引:121
作者
Amelia, Matteo [1 ]
Baroncini, Massimo [1 ]
Credi, Alberto [1 ]
机构
[1] Univ Bologna, Dipartimento Chim G Ciamician, I-40126 Bologna, Italy
关键词
binary logic; luminescence; molecular devices; photochemistry; quinolines;
D O I
10.1002/anie.200802018
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Simple but effective! 8-Methoxyquinoline, an unsophisticated fluorophore, displays both 2:1 multiplexer and 1:2 demultiplexer digital functions (see picture). Protonation of the fluorophore results in completely different optical spectral profiles and multiplexing/demultiplexing behavior is obtained by exploiting the proton-driven reversible modulation of two complementary absorption and fluorescence signals. (Figure Presented). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:6240 / 6243
页数:4
相关论文
共 43 条
[1]   Investigation of an acid-base and redox molecular switch: From bulk the single-molecule level [J].
Al-Kaysi, Rabih O. ;
Luis Bourdelande, Jose ;
Gallardo, Iluminada ;
Guirado, Gonzalo ;
Hernando, Jordi .
CHEMISTRY-A EUROPEAN JOURNAL, 2007, 13 (25) :7066-7074
[2]  
ANDREASSON J, 2007, ANGEW CHEM, V119, P976
[3]   A molecule-based 1: 2 digital demultiplexer [J].
Andreasson, Joakim ;
Straight, Stephen D. ;
Bandyopadhyay, Subhajit ;
Mitchell, Reginald H. ;
Moore, Thomas A. ;
Moore, Ana L. ;
Gust, Devens .
JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (38) :14274-14278
[4]   Molecular 2:1 digital multiplexer [J].
Andreasson, Joakim ;
Straight, Stephen D. ;
Bandyopadhyay, Subhajit ;
Mitchell, Reginald H. ;
Moore, Thomas A. ;
Moore, Ana L. ;
Gust, Devens .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (06) :958-961
[5]  
[Anonymous], 1998, ONES ZEROS UNDERSTAN
[6]   Molecular logic circuits [J].
Balzani, V ;
Credi, A ;
Venturi, M .
CHEMPHYSCHEM, 2003, 4 (01) :49-59
[7]  
BALZANI V, 2008, MOL DEVICES MACHINES, pCH9
[8]   Processing energy and signals by molecular and supramolecular systems [J].
Balzani, Vincenzo ;
Credi, Alberto ;
Venturi, Margherita .
CHEMISTRY-A EUROPEAN JOURNAL, 2008, 14 (01) :26-39
[9]   Excited-state processes in 8-hydroxyquinoline: Photoinduced tautomerization and solvation effects [J].
Bardez, E ;
Devol, I ;
Larrey, B ;
Valeur, B .
JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (39) :7786-7793
[10]   Origins of 'on-off' fluorescent behavior of 8-hydroxyquinoline containing chemosensors [J].
Bronson, RT ;
Montalti, M ;
Prodi, L ;
Zaccheroni, N ;
Lamb, RD ;
Dalley, NK ;
Izatt, RM ;
Bradshaw, JS ;
Savage, PB .
TETRAHEDRON, 2004, 60 (49) :11139-11144