Tris(2-pyridylmethyl)amine Based Ligands in Copper Catalyzed Atom Transfer Radical Addition (ATRA) and Polymerization (ATRP)

被引：0

作者：

Pintauer, Tomislav ^{[1
]}

机构：

[1] Duquesne Univ, Dept Chem & Biochem, Pittsburgh, PA 15282 USA

来源：

CONTROLLED RADICAL POLYMERIZATION, VOL 1: MECHANISMS | 2015年 / 1187卷

基金：

美国国家科学基金会;

关键词：

ALKYNE 3+2 CYCLOADDITION; ELECTRON-TRANSFER; MECHANISTIC ASPECTS; RATE CONSTANTS; COMPLEXES; COORDINATION; OXYGENATION; ACTIVATION; REACTIVITY; EFFICIENT;

D O I：

暂无

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Copper complexes with tris(2-pyridylmethyl)amine (TPMA) ligand are currently among the most active catalysts in atom transfer radical addition (ATRA) and polymerization (ATRP) reactions that utilize reducing agents. Both processes originated from well-known Kharasch addition in which polyhalogenated compounds were added to alkenes via free-radical means. The main focus of this article is to review structural and mechanistic aspects of ATRA and ATRP reactions catalyzed by copper complexes with TPMA ligand. Special emphasis will be placed on recently developed substituted TPMA based ligands that contain electron donating groups.

引用

页码：105 / 128

页数：24

共 110 条

[21] Structural Comparison of Copper(I) and Copper(II) Complexes with Tris(2-pyridylmethyl)amine Ligand [J].

Eckenhoff, William T. ;

Pintauer, Tomislav .

INORGANIC CHEMISTRY, 2010, 49 (22) :10617-10626

[22] Copper Catalyzed Atom Transfer Radical Addition (ATRA) and Cyclization (ATRC) Reactions in the Presence of Reducing Agents [J].

Eckenhoff, William T. ;

Pintauer, Tomislav .

CATALYSIS REVIEWS-SCIENCE AND ENGINEERING, 2010, 52 (01) :1-59

[23] The persistent radical effect: A principle for selective radical reactions and living radical polymerizations [J].

Fischer, H .

CHEMICAL REVIEWS, 2001, 101 (12) :3581-3610

[24]

Fischer H, 1999, J POLYM SCI POL CHEM, V37, P1885, DOI 10.1002/(SICI)1099-0518(19990701)37:13<1885::AID-POLA1>3.0.CO

[25]

2-1

[26]

FISCHER H, 1986, J AM CHEM SOC, V108, P3925, DOI 10.1021/ja00274a012

[27] The rate of O2 and CO binding to a copper complex, determined by a "flash-and-trap" technique, exceeds that for hemes [J].

Fry, HC ;

Scaltrito, DV ;

Karlin, KD ;

Meyer, GJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (39) :11866-11871

[28] Catalyst performance in "click" coupling reactions of polymers prepared by ATRP: Ligand and metal effects [J].

Golas, Patricia L. ;

Tsarevsky, Nicolay V. ;

Sumerlin, Brent S. ;

Matyjaszewski, Krzysztof .

MACROMOLECULES, 2006, 39 (19) :6451-6457

[29] The effect of N-methylation of tetra-aza-alkane copper complexes on the axial binding of anions [J].

Golub, G ;

Lashaz, A ;

Cohen, H ;

Paoletti, P ;

Bencini, A ;

Valtancoli, B ;

Meyerstein, D .

INORGANICA CHIMICA ACTA, 1997, 255 (01) :111-115

[30]

Goto A, 1999, MACROMOL RAPID COMM, V20, P633, DOI 10.1002/(SICI)1521-3927(19991201)20:12<633::AID-MARC633>3.0.CO

← 1 2 3 4 5 6 7 8 9 10 →