Tris(2-pyridylmethyl)amine Based Ligands in Copper Catalyzed Atom Transfer Radical Addition (ATRA) and Polymerization (ATRP)

被引：0

作者：

Pintauer, Tomislav ^{[1
]}

机构：

[1] Duquesne Univ, Dept Chem & Biochem, Pittsburgh, PA 15282 USA

来源：

CONTROLLED RADICAL POLYMERIZATION, VOL 1: MECHANISMS | 2015年 / 1187卷

基金：

美国国家科学基金会;

关键词：

ALKYNE 3+2 CYCLOADDITION; ELECTRON-TRANSFER; MECHANISTIC ASPECTS; RATE CONSTANTS; COMPLEXES; COORDINATION; OXYGENATION; ACTIVATION; REACTIVITY; EFFICIENT;

D O I：

暂无

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Copper complexes with tris(2-pyridylmethyl)amine (TPMA) ligand are currently among the most active catalysts in atom transfer radical addition (ATRA) and polymerization (ATRP) reactions that utilize reducing agents. Both processes originated from well-known Kharasch addition in which polyhalogenated compounds were added to alkenes via free-radical means. The main focus of this article is to review structural and mechanistic aspects of ATRA and ATRP reactions catalyzed by copper complexes with TPMA ligand. Special emphasis will be placed on recently developed substituted TPMA based ligands that contain electron donating groups.

引用

页码：105 / 128

页数：24

共 110 条

[1] SYNTHESIS, STRUCTURE, AND SPECTROSCOPIC PROPERTIES OF COPPER(II) COMPOUNDS CONTAINING NITROGEN SULFUR DONOR LIGANDS - THE CRYSTAL AND MOLECULAR-STRUCTURE OF AQUA[1,7-BIS(N-METHYLBENZIMIDAZOL-2'-YL)-2,6-DITHIAHEPTANE]COPPER(II) PERCHLORATE
ADDISON, AW
RAO, TN
REEDIJK, J
VANRIJN, J
VERSCHOOR, GC
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1984, (07): : 1349 - 1356
[2] Influence of coordination geometry upon copper(II/I) redox potentials. Physical parameters for twelve copper tripodal ligand complexes
Ambundo, EA
Deydier, MV
Grall, AJ
Aguera-Vega, N
Dressel, LT
Cooper, TH
Heeg, MJ
Ochrymowycz, LA
Rorabacher, DB
[J]. INORGANIC CHEMISTRY, 1999, 38 (19) : 4233 - 4242
[3] PYRIDINE DERIVATIVES AS COMPLEX FORMERS .8. PRODUCTION OF A NEW 4 AND A NEW 6 TOOTH LIGAND
ANDEREGG, G
WENK, F
[J]. HELVETICA CHIMICA ACTA, 1967, 50 (08) : 2330 - &
[4] SPECTROSCOPIC AND THEORETICAL-STUDIES OF AN END-ON PEROXIDE-BRIDGED COUPLED BINUCLEAR COPPER(II) MODEL COMPLEX OF RELEVANCE TO THE ACTIVE-SITES IN HEMOCYANIN AND TYROSINASE
BALDWIN, MJ
ROSS, PK
PATE, JE
TYEKLAR, Z
KARLIN, KD
SOLOMON, EI
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (23) : 8671 - 8679
[5] Kinetic Studies of the Initiation Step in Copper Catalyzed Atom Transfer Radical Addition (ATRA) in the Presence of Free Radical Diazo Initiators as Reducing Agents
Balili, Marielle Nicole C.
Pintauer, Tomislav
[J]. INORGANIC CHEMISTRY, 2010, 49 (12) : 5642 - 5649
[6] Persistent Radical Effect in Action: Kinetic Studies of Copper-Catalyzed Atom Transfer Radical Addition in the Presence of Free-Radical Diazo Initiators as Reducing Agents
Balili, Marielle Nicole C.
Pintauer, Tomislav
[J]. INORGANIC CHEMISTRY, 2009, 48 (18) : 9018 - 9026
[7] Advancements in the mechanistic understanding of the copper-catalyzed azide-alkyne cycloaddition
Berg, Regina
Straub, Bernd F.
[J]. BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 2013, 9 : 2715 - 2750
[8] Synthesis and characterization of ruthenium(II) complexes with polypicolylamine ligands
Bjernemose, J
Hazell, A
McKenzie, CJ
Mahon, MF
Nielsen, LP
Raithby, PR
Simonsen, O
Toftlund, H
Wolny, JA
[J]. POLYHEDRON, 2003, 22 (06) : 875 - 885
[9] Thermodynamic Properties of Copper Complexes Used as Catalysts in Atom Transfer Radical Polymerization
Bortolamei, Nicola
Isse, Abdirisak A.
Di Marco, Valerio B.
Gennaro, Armando
Matyjaszewski, Krzysztof
[J]. MACROMOLECULES, 2010, 43 (22) : 9257 - 9267
[10] Controlled/living radical polymerization: Features, developments, and perspectives
Braunecker, Wade A.
Matyjaszewski, Krzysztof
[J]. PROGRESS IN POLYMER SCIENCE, 2007, 32 (01) : 93 - 146

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