Pd/CaCO3 in liquid poly(ethylene glycol) (PEG):: an easy and efficient recycle system for partial reduction of alkynes to cis-olefins under a hydrogen atmosphere

被引：70
作者：
Chandrasekhar, S [1 ]
Narsihmulu, C [1 ]
Chandrashekar, G [1 ]
Shyamsunder, T [1 ]
机构：
[1] Indian Inst Chem Technol, Hyderabad 500007, Andhra Pradesh, India
来源：
TETRAHEDRON LETTERS | 2004年 / 45卷 / 11期
关键词：
hydrogenation; Lindlar's catalyst; PEG; recycling;
D O I：
10.1016/j.tetlet.2004.01.097
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Lindlar's catalyst (Pd/CaCO3) in PEG (400) has been found to be the most reusable reaction medium for selective reduction of alkynes to cis-olefins. The catalyst and PEG were recycled five times without loss of activity. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码：2421 / 2423
页数：3
相关论文
共 34 条
  • [1] Soluble polymer-supported convergent parallel library synthesis
    Ahn, JM
    Wentworth, P
    Janda, KD
    [J]. CHEMICAL COMMUNICATIONS, 2003, (04) : 480 - 481
  • [2] [Anonymous], ORGANIC SYNTHESIS WA
  • [3] ENZYMATIC PEPTIDE SYNTHESES IN ORGANIC-SOLVENT MEDIATED BY MODIFIED ALPHA-CHYMOTRYPSIN
    BABONNEAU, MT
    JACQUIER, R
    LAZARO, R
    VIALLEFONT, P
    [J]. TETRAHEDRON LETTERS, 1989, 30 (21) : 2787 - 2790
  • [4] BADONE D, 1987, SYNTHESIS-STUTTGART, P920
  • [5] Supercritical fluids in heterogeneous catalysis
    Baiker, A
    [J]. CHEMICAL REVIEWS, 1999, 99 (02) : 453 - 473
  • [6] Developments in CO2 research
    Behles, JA
    DeSimone, JM
    [J]. PURE AND APPLIED CHEMISTRY, 2001, 73 (08) : 1281 - 1285
  • [7] HYDROPHOBIC EFFECTS ON SIMPLE ORGANIC-REACTIONS IN WATER
    BRESLOW, R
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 1991, 24 (06) : 159 - 164
  • [8] Poly(ethylene glycol) (PEG) as a reusable solvent medium for organic synthesis. Application in the Heck reaction
    Chandrasekhar, S
    Narsihmulu, C
    Sultana, SS
    Reddy, NR
    [J]. ORGANIC LETTERS, 2002, 4 (25) : 4399 - 4401
  • [9] Osmium tetroxide in poly(ethylene glycol) (PEG): a recyclable reaction medium for rapid asymmetric dihydroxylation under Sharpless conditions
    Chandrasekhar, S
    Narsihmulu, C
    Sultana, SS
    Reddy, NR
    [J]. CHEMICAL COMMUNICATIONS, 2003, (14) : 1716 - 1717
  • [10] New directions in inorganic and metal-organic coordination chemistry in supercritical fluids
    Darr, JA
    Poliakoff, M
    [J]. CHEMICAL REVIEWS, 1999, 99 (02) : 495 - 541
1234