Synthesis of polycyclic hydrocarbons by palladium-catalyzed cross-coupling reactions of vinylic bromides with diphenylacetylene

被引：22

作者：

Dyker, G

Siemsen, P

Sostmann, S

Wiegand, A

Dix, I

Jones, PG

机构：

[1] TECH UNIV CAROLO WILHELMINA BRAUNSCHWEIG,INST ORGAN CHEM,D-38106 BRAUNSCHWEIG,GERMANY

[2] TECH UNIV CAROLO WILHELMINA BRAUNSCHWEIG,INST ANORGAN CHEM & ANALYT CHEM,D-38106 BRAUNSCHWEIG,GERMANY

来源：

CHEMISCHE BERICHTE-RECUEIL | 1997年 / 130卷 / 02期

关键词：

polycycles; hydrocarbons; palladium catalysis; domino processes; cross coupling; homogeneous catalysis;

D O I：

10.1002/cber.19971300220

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Vinylic bromides of type 1 undergo cross-coupling reactions with diphenylacetylene (5) leading to various polycyclic hydrocarbons. The ratio of the 1:1 to the 1:2 products can readily be controlled by varying the reaction conditions.

引用

页码：261 / 265

页数：5

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