Rhodium(III)-Catalyzed Regioselective Decarboxylative Cyclization for the Synthesis of 4H-Furo[3,2-c]chromen-4-one Derivatives

被引：34
|
作者：
Zha, Dandan [1 ]
Li, Hongji [1 ]
Li, Shiqing [1 ]
Wang, Lei [1 ,2 ]
机构：
[1] Huaibei Normal Univ, Dept Chem, Huaibei 235000, Anhui, Peoples R China
[2] Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2017年 / 359卷 / 03期
基金：
美国国家科学基金会;
关键词：
decarboxylation; furans; hypervalent iodine reagent; propiolic acids; Rh catalysis; ALKYNYL CARBOXYLIC-ACIDS; C-H ACTIVATION; POTASSIUM OXALATE MONOESTERS; ALPHA-OXOCARBOXYLIC ACIDS; BOND FORMATION; DIRECT ACCESS; ARYL HALIDES; CATALYZED DECARBOXYLATION; ORTHO-HETEROARYLATION; DIARYLIODONIUM SALTS;
D O I：
10.1002/adsc.201600974
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
This contribution describes a regioselective cyclization of hypervalent iodine reagents (HIR) with propiolic acids in the presence of a rhodium catalyst. The mild decarboxylation can tolerate a wide range of groups and generates 4H-furo[3,2-c] chro-men-4-one derivatives in good isolated yields.
引用
收藏
页码：467 / 475
页数：9
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