An unusual seven-connected lead borate constructed by different cluster building units of {B6} and {Pb6}

被引：19
作者：
Tian, Han-Rui [1 ]
Wang, Wen-Hua [1 ]
Zhang, Xiao-Ping [1 ]
Feng, Yun-Long [1 ]
Cheng, Jian-Wen [1 ]
机构：
[1] Zhejiang Normal Univ, Inst Phys Chem, Key Lab, Minist Educ Adv Catalysis Mat, Jinhua 321004, Zhejiang, Peoples R China
来源：
DALTON TRANSACTIONS | 2013年 / 42卷 / 04期
基金：
中国国家自然科学基金;
关键词：
METAL-ORGANIC FRAMEWORKS; NONLINEAR-OPTICAL CRYSTAL; MOLECULAR-SIEVES; ALUMINOBORATE; CHANNELS; BO3; CHEMISTRY; ZEOLITES; ALKALINE; DESIGN;
D O I：
10.1039/c2dt32364h
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new 3D lead borate Pb6B6O14(OH)(2)(H2O), built by different cluster building units of B6O14(OH) {B-6} and Pb6O5(OH) {Pb-6}, has been obtained under mild hydrothermal conditions. Each {B-6} cluster is linked with seven {Pb-6} clusters and vice versa that give rise to the first 7-connected lead borate network.
引用
收藏
页码：894 / 897
页数：4
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