Performance of an Electrochemical double layer capacitor based on coconut shell active material and ionic liquid as an electrolyte

被引:37
作者
Galinski, Maciej [1 ]
Babel, Krzysztof [2 ]
Jurewicz, Krzysztof [1 ]
机构
[1] Poznan Univ Tech, Fac Chem Technol, PL-60965 Poznan, Poland
[2] Poznan Univ Life Sci, PL-60637 Poznan, Poland
关键词
Room temperature ionic liquid; EMImBE(4); Electrochemical double layer capacitor (EDLC); Activated carbon; PORE-SIZE; SUPERCAPACITORS; CARBONS; TETRAFLUOROBORATE;
D O I
10.1016/j.jpowsour.2012.11.048
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
EDLCs based on the modified coconut shell raw material were manufactured with 1-Ethy1-3-methylimidazolium tetrafluoroborate (EMImBF(4)) as an electrolyte and a typical organic electrolyte based on acetonitrile. Three types of modification of the carbon material with different micro- to mesopore ratios were applied as the positive or negative electrode and tested. Obtained results showed different characteristic capacitances of 150-350 Fg(-1), strongly dependent on the type of carbon material. Asymmetric EDLCs were manufactured from different carbon materials as positive and negative electrodes and a mass electrode fitting provided with an EDLC working at 3 V with a specific energy of 68.6 Wh kg(-1) and power density of 36 W kg(-1). (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:83 / 88
页数:6
相关论文
共 28 条
[11]   Principles and applications of electrochemical capacitors [J].
Kötz, R ;
Carlen, M .
ELECTROCHIMICA ACTA, 2000, 45 (15-16) :2483-2498
[12]   High voltage electrochemical double layer capacitor containing mixtures of ionic liquids and organic carbonate as electrolytes [J].
Krause, A. ;
Balducci, A. .
ELECTROCHEMISTRY COMMUNICATIONS, 2011, 13 (08) :814-817
[13]   Electrical Double Layer Capacitors Based on Two 1-Ethyl-3-Methylimidazolium Ionic Liquids with Different Anions [J].
Kurig, H. ;
Vestli, M. ;
Jaenes, A. ;
Lust, E. .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2011, 14 (08) :A120-A122
[14]   Electrochemical Characteristics of Carbide-Derived Carbon|1-Ethyl-3-methylimidazolium Tetrafluoroborate Supercapacitor Cells [J].
Kurig, Heisi ;
Jaenes, Alar ;
Lust, Enn .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2010, 157 (03) :A272-A279
[15]   Relation between the ion size and pore size for an electric double-layer capacitor [J].
Largeot, Celine ;
Portet, Cristelle ;
Chmiola, John ;
Taberna, Pierre-Louis ;
Gogotsi, Yury ;
Simon, Patrice .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (09) :2730-+
[16]   Performance of carbon-carbon supercapacitors based on organic, aqueous and ionic liquid electrolytes [J].
Lewandowski, Andrzej ;
Olejniczak, Angelika ;
Galinski, Maciej ;
Stepniak, Izabela .
JOURNAL OF POWER SOURCES, 2010, 195 (17) :5814-5819
[17]   Microelectrode Study of Pore Size, Ion Size, and Solvent Effects on the Charge/Discharge Behavior of Microporous Carbons for Electrical Double-Layer Capacitors [J].
Lin, R. ;
Taberna, P. L. ;
Chmiola, J. ;
Guay, D. ;
Gogotsi, Y. ;
Simon, P. .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2009, 156 (01) :A7-A12
[18]   Strategies for high-performance supercapacitors for HEV [J].
Mastragostino, Marina ;
Soavi, Francesca .
JOURNAL OF POWER SOURCES, 2007, 174 (01) :89-93
[19]  
Miller JR, 2008, ELECTROCHEM SOC INTE, V17, P53
[20]   Physical and electrochemical properties of 1-alkyl-3-methylimidazolium tetrafluoroborate for electrolyte [J].
Nishida, T ;
Tashiro, Y ;
Yamamoto, M .
JOURNAL OF FLUORINE CHEMISTRY, 2003, 120 (02) :135-141