First observation of excited triplet dimers with strong intramolecular interactions:: planar binuclear phthalocyanines

被引：41

作者：

Ishii, K

Kobayashi, N ^{[1
]}

Higashi, K

Osa, T

Lelièvre, D

Simon, J

Yamauchi, S

机构：

[1] Tohoku Univ, Grad Sch Sci, Dept Chem, Sendai, Miyagi 9808578, Japan

[2] Tohoku Univ, Inst Pharmaceut, Sendai, Miyagi 9808578, Japan

[3] Tohoku Univ, Inst Chem React Sci, Sendai, Miyagi 9808578, Japan

[4] Ecole Super Phys & Chim Ind, CNRS, F-75231 Paris 05, France

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 11期

关键词：

D O I：

10.1039/a900347i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Zero field splitting parameters of planar binuclear phthalocyanines in the lowest excited triplet state have been obtained by using a time-resolved EPR method to show a delocalization of excitation over two phthalocyanine units for a homodimer and a contribution from a charge transfer configuration for a heterodimer.

引用

页码：969 / 970

页数：2

共 24 条

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