Characterization of [8-ethyl]-chlorophyll c3 from Emiliania huxleyi

被引：19
作者：
Alvarez, Susana [2 ]
Zapata, Manuel [1 ]
Garrido, Jose L. [1 ]
Vaz, Belen [2 ]
机构：
[1] Inst Invest Marinas CSIC, Vigo 36208, Spain
[2] Univ Vigo, Fac Quim, Dept Quim Organ, Vigo 36310, Spain
来源：
CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 44期
关键词：
CHLOROPHYLL-C; ABSOLUTE-CONFIGURATION; ALGAL CAROTENOIDS; LIGHT; PIGMENTS; PRYMNESIOPHYCEAE; PHYTOPLANKTON; COCCOLITHOPHORE; FAMILY; BLOOMS;
D O I：
10.1039/c2cc31329d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We report herein the isolation and complete characterization of a member of the chlorophyll c family, designated as [8-ethyl]-chlorophyll c(3) ([8-ethyl]-chl c(3)). Structural elucidation of this pigment rested on the analysis of mono- and bidimensional NMR, UV-VIS spectroscopy and ESI-MS data, and the configuration at the 13(2) position on chiral HPLC analysis.
引用
收藏
页码：5500 / 5502
页数：3
相关论文
共 33 条
[1]   Improved detection and characterization of fucoxanthin-type carotenoids:: Novel pigments in Emiliania huxleyi (Prymnesiophyceae) [J].
Airs, RL ;
Llewellyn, CA .
JOURNAL OF PHYCOLOGY, 2006, 42 (02) :391-399
[2]   ALGAL CAROTENOIDS .16. NEW FUCOXANTHIN-RELATED CAROTENOIDS FROM COCCOLITHUS-HUXLEYI [J].
ARPIN, N ;
SVEC, WA ;
LIAAENJENSEN, S .
PHYTOCHEMISTRY, 1976, 15 (04) :529-532
[3]   Blooms of Emiliania huxleyi are sinks of atmospheric carbon dioxide: A field and mesocosm study derived simulation [J].
Buitenhuis, ET ;
van der Wal, P ;
de Baar, HJW .
GLOBAL BIOGEOCHEMICAL CYCLES, 2001, 15 (03) :577-587
[4]   Dimethyl sulphide biogeochemistry within a coccolithophore bloom (DISCO): an overview [J].
Burkill, PH ;
Archer, SD ;
Robinson, C ;
Nightingale, PD ;
Groom, SB ;
Tarran, GA ;
Zubkov, MV .
DEEP-SEA RESEARCH PART II-TOPICAL STUDIES IN OCEANOGRAPHY, 2002, 49 (15) :2863-2885
[5]   A Red-Shifted Chlorophyll [J].
Chen, Min ;
Schliep, Martin ;
Willows, Robert D. ;
Cai, Zheng-Li ;
Neilan, Brett A. ;
Scheer, Hugo .
SCIENCE, 2010, 329 (5997) :1318-1319
[6]   Algal carotenoids.: Part 64.: Structure and chemistry of 4-keto-19′-hexanoyloxyfucoxanthin with a novel carotenoid end group [J].
Egeland, ES ;
Garrido, JL ;
Zapata, M ;
Maestro, MA ;
Liaaen-Jensen, S .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 2000, (08) :1223-1230
[7]   THE STRUCTURE OF CHLOROPHYLL-C3, A NOVEL MARINE PHOTOSYNTHETIC PIGMENT [J].
FOOKES, CJR ;
JEFFREY, SW .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (23) :1827-1828
[8]   The main nonpolar chlorophyll c from Emiliania huxleyi (Prymnesiophyceae) is a chlorophyll c2-monogalactosyldiacylglyceride ester:: a mass spectrometry study [J].
Garrido, JL ;
Otero, J ;
Maestro, MA ;
Zapata, M .
JOURNAL OF PHYCOLOGY, 2000, 36 (03) :497-505
[9]   SPECTRAL CHARACTERIZATION OF NEW CHLOROPHYLL-C PIGMENTS ISOLATED FROM EMILIANIA-HUXLEYI (PRYMNESIOPHYCEAE) BY HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHY [J].
GARRIDO, JL ;
ZAPATA, M ;
MUNIZ, S .
JOURNAL OF PHYCOLOGY, 1995, 31 (05) :761-768
[10]   Detection of new pigments from Emiliania huxleyi (Prymnesiophyceae) by high-performance liquid chromatography, liquid chromatography-mass spectrometry, visible spectroscopy, and fast atom bombardment mass spectrometry [J].
Garrido, JL ;
Zapata, M .
JOURNAL OF PHYCOLOGY, 1998, 34 (01) :70-78
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