Aryl ether dendrimers with an interior metalloporphyrin functionality as a spectroscopic probe: Interpenetrating interaction with dendritic imidazoles

被引:147
作者
Tomoyose, Y
Jiang, DL
Jin, RH
Aida, T
Yamashita, T
Horie, K
Yashima, E
Okamoto, Y
机构
[1] UNIV TOKYO, GRAD SCH ENGN, DEPT CHEM & BIOTECHNOL, BUNKYO KU, TOKYO 113, JAPAN
[2] NAGOYA UNIV, FAC ENGN, DEPT APPL CHEM, CHIKUSA KU, NAGOYA, AICHI 46401, JAPAN
关键词
D O I
10.1021/ma960575+
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A dendritic molecule (zinc porphyrin, LnPZn) with an interior metalloporphyrin functionality is covalently linked to aryl ether dendritic arrays. The interior properties of the dendritic zinc porphyrins are investigated by spectroscopic analysis and their interpenetrating interaction with dendritic imidazoles are highlighted. A structure-interior property relationship for an aryl dendrimer family is observed by using the interior metalloporphyrin functionality as a spectroscopic probe.
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页码:5236 / 5238
页数:3
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