Aryl ether dendrimers with an interior metalloporphyrin functionality as a spectroscopic probe: Interpenetrating interaction with dendritic imidazoles

被引：147
作者：
Tomoyose, Y
Jiang, DL
Jin, RH
Aida, T
Yamashita, T
Horie, K
Yashima, E
Okamoto, Y
机构：
[1] UNIV TOKYO, GRAD SCH ENGN, DEPT CHEM & BIOTECHNOL, BUNKYO KU, TOKYO 113, JAPAN
[2] NAGOYA UNIV, FAC ENGN, DEPT APPL CHEM, CHIKUSA KU, NAGOYA, AICHI 46401, JAPAN
来源：
MACROMOLECULES | 1996年 / 29卷 / 15期
关键词：
D O I：
10.1021/ma960575+
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A dendritic molecule (zinc porphyrin, LnPZn) with an interior metalloporphyrin functionality is covalently linked to aryl ether dendritic arrays. The interior properties of the dendritic zinc porphyrins are investigated by spectroscopic analysis and their interpenetrating interaction with dendritic imidazoles are highlighted. A structure-interior property relationship for an aryl dendrimer family is observed by using the interior metalloporphyrin functionality as a spectroscopic probe.
引用
收藏
页码：5236 / 5238
页数：3
相关论文
共 13 条
[1]  
DANDLIKER PJ, 1994, ANGEW CHEM INT EDIT, V33, P1739, DOI 10.1002/anie.199417391
[2]   FUNCTIONAL POLYMERS AND DENDRIMERS - REACTIVITY, MOLECULAR ARCHITECTURE, AND INTERFACIAL ENERGY [J].
FRECHET, JMJ .
SCIENCE, 1994, 263 (5154) :1710-1715
[3]   MOLECULAR BALL-BEARINGS - THE UNUSUAL MELT VISCOSITY BEHAVIOR OF DENDRITIC MACROMOLECULES [J].
HAWKER, CJ ;
FARRINGTON, PJ ;
MACKAY, ME ;
WOOLEY, KL ;
FRECHET, JMJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (15) :4409-4410
[4]   PREPARATION OF POLYMERS WITH CONTROLLED MOLECULAR ARCHITECTURE - A NEW CONVERGENT APPROACH TO DENDRITIC MACROMOLECULES [J].
HAWKER, CJ ;
FRECHET, JMJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (21) :7638-7647
[5]   SOLVATOCHROMISM AS A PROBE OF THE MICROENVIRONMENT IN DENDRITIC POLYETHERS - TRANSITION FROM AN EXTENDED TO A GLOBULAR STRUCTURE [J].
HAWKER, CJ ;
WOOLEY, KL ;
FRECHET, JMJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (10) :4375-4376
[6]   ENCAPSULATION OF GUEST MOLECULES INTO A DENDRITIC BOX [J].
JANSEN, JFGA ;
DEBRABANDERVANDENBERG, EMM ;
MEIJER, EW .
SCIENCE, 1994, 266 (5188) :1226-1229
[7]   CAGED PORPHYRIN - THE 1ST DENDRITIC MOLECULE HAVING A CORE PHOTOCHEMICAL FUNCTIONALITY [J].
JIN, RH ;
AIDA, T ;
INOUE, S .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (16) :1260-1262
[8]   CHEMISTRY WITHIN A UNIMOLECULAR MICELLE PRECURSOR - BORON SUPERCLUSTERS BY SITE-SPECIFIC AND DEPTH-SPECIFIC TRANSFORMATIONS OF DENDRIMERS .37. CHEMISTRY OF MICELLES [J].
NEWKOME, GR ;
MOOREFIELD, CN ;
KEITH, JM ;
BAKER, GR ;
ESCAMILLA, GH .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1994, 33 (06) :666-668
[9]   ROUTES TO DENDRITIC NETWORKS - BIS-DENDRIMERS BY COUPLING OF CASCADE MACROMOLECULES THROUGH METAL CENTERS [J].
NEWKOME, GR ;
GUTHER, R ;
MOOREFIELD, CN ;
CARDULLO, F ;
ECHEGOYEN, L ;
PEREZCORDERO, E ;
LUFTMANN, H .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (18) :2023-2026
[10]   CHARACTERIZATION OF STARBURST DENDRIMERS BY ELECTRON-PARAMAGNETIC-RESONANCE .2. POSITIVELY CHARGED NITROXIDE RADICALS OF VARIABLE CHAIN-LENGTH USED AS SPIN PROBES [J].
OTTAVIANI, MF ;
COSSU, E ;
TURRO, NJ ;
TOMALIA, DA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (15) :4387-4398
12