Assessment of duplex coating combining plasma electrolytic oxidation and polymer layer on AZ31 magnesium alloy

被引:117
作者
Arrabal, R. [1 ]
Mota, J. M. [2 ]
Criado, A. [1 ]
Pardo, A. [1 ]
Mohedano, M. [1 ]
Matykina, E. [1 ]
机构
[1] Univ Complutense, Fac Ciencias Quim, Dept Ciencia Mat, E-28040 Madrid, Spain
[2] Desarrollo & Control Tecnol, Alcala De Henares 28806, Spain
关键词
Magnesium; Plasma electrolytic oxidation; Corrosion; Polymer coating; Impact; ac/dc/ac; MG-AL ALLOYS; CORROSION PROTECTION; PEO COATINGS; RESISTANCE; AZ91D; ENVIRONMENTS; CHLORIDE;
D O I
10.1016/j.surfcoat.2012.05.091
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Mechanical and corrosion tests were performed on a polymer-coated AZ31 magnesium alloy pre-treated by plasma electrolytic oxidation (PEO). Results were compared with a fluorotitanate-zirconate conversion coating pre-treatment. Mechanical performance was assessed by standardized adhesion (ISO 2409:2007), impact (ISO 6272-1:2004) and impact + adhesion (ISO 6272/ASTMD2794) pass/fail tests. Corrosion behavior was monitored using electrochemical impedance spectroscopy (EIS), ac/dc/ac measurements and continuous exposure to salt fog per ASTM B117 and cyclic exposure per VDA 621-415 (VDA). The PEO + polymer coating revealed lower impact resistance but better corrosion resistance than the Ti/Zr + polymer coating. The ac/dc/ac procedure demonstrated to be faster than EIS measurements for evaluation of the corrosion performance of studied coatings. (c) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:4692 / 4703
页数:12
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