Electrochromic features of hybrid films composed of polyaniline and metal hexacyanoferrate

Hybrid organic/inorganic films, composed of polyaniline (PANI) matrix and Prussian blue-Like nickel hexacyanoferrate redox centers, showed reversible electrochromic behavior in acidic potassium salt electrolytes. The system's coloration properties were assessed from various spectroelectrochemical measurements including voltabsorptometry that involved monitoring of the time-derivative signal of absorbance at 700 and 410 mn as a function of linearly scanned potential. Gold-covered foil was used as a conductive, optically transparent, substrate onto which the composite film was electrodeposited by potential cycling in the mixture for modification consisting of aniline monomer, Ni(2+), Fe(CN)(6)(3-) and electrolyte containing K(+) and H(+) ions. An important feature of hybrid (composite) material was that its electrochromic properties were dominated by color changes occurring in the PANI component. Coloration originating from nickel hexacyanoferrate barely affected the system's electrochromic characteristics. But the cyanometallate redox centers distributed in the PANI matrix behaved reversibly as expected for a system capable of fast charge transport. (C) 2001 Elsevier Science Ltd. All rights reserved.