Charge Transmission and Recombination in the Dye-Sensitized Solar Cells Based on Mn-Doped TiO2 Thin Films

被引:2
作者
Liu Qiuping [1 ,2 ]
Zhou Yang [3 ]
Huang Huijuan [4 ]
Guo Quanjiang [2 ]
Zhao Xianhui [1 ]
Yuan Lin [3 ]
机构
[1] Beijing Jiaotong Univ, Sch Mech Elect & Control Engn, Beijing 100044, Peoples R China
[2] Jiangxi Univ Sci & Technol, Nanchang 330013, Jiangxi, Peoples R China
[3] Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Key Lab Photochem, Beijing 100190, Peoples R China
[4] Jiujiang Vocat & Tech Coll, Jiujiang 332008, Peoples R China
来源
MATERIALS FOR ENERGY CONVERSION AND STORAGE | 2012年 / 519卷
关键词
solar cells; Mn-doped film; electron lifetime; transport time; charge recombination; EFFICIENCY; ELECTRODE;
D O I
10.4028/www.scientific.net/KEM.519.53
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Mn salts[MnSO4]-doped TiO2 electrodes thin film was synthesized by the hydrothermal method. To prepare the working electrode, The TiO2 or Mn-doped TiO2 slurry was coated onto the fluorine-doped tin oxide glass substrate by the doctor blade method and was then sintered at 450 degrees C. X-ray photoelectron spectroscopy (XPS) data indicated that the doped Mn ions exist in forms of Mn7+. This study show a photovoltaic efficiency of 5.15%, which is higher than that of the undoped TiO2 thin film (4.14%) and increase photovoltage and fill factors by 13.2% from 455 mV to 515mV, 39.3% from 499 to 695 respectively.
引用
收藏
页码:53 / +
页数:2
相关论文
共 9 条
  • [1] Aranayake, 2004, COORD CHEM REV, V248, P1277
  • [2] Ultrafast studies of electron injection in Ru dye sensitized SnO2 nanocrystalline thin film
    Bauer, C
    Boschloo, G
    Mukhtar, E
    Hagfeldt, A
    [J]. INTERNATIONAL JOURNAL OF PHOTOENERGY, 2002, 4 (01) : 17 - 20
  • [3] Conversion of sunlight to electric power by nanocrystalline dye-sensitized solar cells
    Grätzel, M
    [J]. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2004, 164 (1-3) : 3 - 14
  • [4] Comparison of electrode structures and photovoltaic properties of porphyrin-sensitized solar cells with TiO2 and Nb, Ge, Zr-added TiO2 composite electrodes
    Imahori, Hiroshi
    Hayashi, Shinya
    Umeyama, Tomokazu
    Eu, Seunghun
    Oguro, Akane
    Kang, Soonchul
    Matano, Yoshihiro
    Shishido, Tetsuya
    Ngamsinlapasathian, Supachai
    Yoshikawa, Susumu
    [J]. LANGMUIR, 2006, 22 (26) : 11405 - 11411
  • [5] H2 evolution from an aqueous methanol solution on SrTiO3 photocatalysts codoped with chromium and tantalum ions under visible light irradiation
    Ishii, T
    Kato, H
    Kudo, A
    [J]. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2004, 163 (1-2) : 181 - 186
  • [6] Influence of light scattering particles in the TiO2 photoelectrode for solid-state dye-sensitized solar cell
    Kang, Soon Hyung
    Kim, Jae-Yup
    Kim, Hyun Sik
    Koh, Haeng-Deog
    Lee, Jae-Suk
    Sung, Yung-Eun
    [J]. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2008, 200 (2-3) : 294 - 300
  • [7] Modification of a TiO2 photoanode by using Cr-doped TiO2 with an influence on the photovoltaic efficiency of a dye-sensitized solar cell
    Kim, Cham
    Kim, Ki-Soo
    Kim, Ho Young
    Han, Yoon Soo
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2008, 18 (47) : 5809 - 5814
  • [8] A LOW-COST, HIGH-EFFICIENCY SOLAR-CELL BASED ON DYE-SENSITIZED COLLOIDAL TIO2 FILMS
    OREGAN, B
    GRATZEL, M
    [J]. NATURE, 1991, 353 (6346) : 737 - 740
  • [9] Electronic-insulating coating of CaCO3 on TiO2 electrode in dye-sensitized solar cells:: Improvement of electron lifetime and efficiency
    Wang, ZS
    Yanagida, M
    Sayama, K
    Sugihara, H
    [J]. CHEMISTRY OF MATERIALS, 2006, 18 (12) : 2912 - 2916