Chiral Acyclic Diaminocarbene Complexes: a New Opportunity for Gold Asymmetric Catalysis

被引:23
作者
Barbazanges, Marion [1 ]
Fensterbank, Louis [1 ]
机构
[1] Univ Sorbonne, Univ Paris 06, Inst Parisien Chim Mol UMR CNRS 7201, F-75005 Paris, France
关键词
acyclic diaminocarbene; chirality; cyclization; gold; homogeneous catalysis; ENANTIOSELECTIVE SYNTHESIS; COUNTERION STRATEGY; PI-INTERACTIONS; CARBENES; HYDROALKOXYLATION; CYCLOPROPANATION; 1,6-ENYNES; ALDEHYDES; PATHWAYS; ALLENES;
D O I
10.1002/cctc.201200224
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
引用
收藏
页码:1065 / 1066
页数:2
相关论文
共 47 条
[1]  
Aikawa K., 2009, Angew. Chem, V121, P6189
[2]   Synergistic Effect: Hydroalkoxylation of Allenes through Combination of Enantiopure BIPHEP-Gold Complexes and Chiral Anions [J].
Aikawa, Kohsuke ;
Kojima, Masafumi ;
Mikami, Koichi .
ADVANCED SYNTHESIS & CATALYSIS, 2010, 352 (18) :3131-3135
[3]   Axial Chirality Control of Gold(biphep) Complexes by Chiral Anions: Application to Asymmetric Catalysis [J].
Aikawa, Kohsuke ;
Kojima, Masafumi ;
Mikami, Koichi .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (33) :6073-6077
[4]   Gold-Catalyzed [4C+2C] Cycloadditions of Allenedienes, including an Enantioselective Version with New Phosphoramidite-Based Catalysts: Mechanistic Aspects of the Divergence between [4C+3C] and [4C+2C] Pathways [J].
Alonso, Isaac ;
Trillo, Beatriz ;
Lopez, Fernando ;
Montserrat, Sergi ;
Ujaque, Gregori ;
Castedo, Luis ;
Lledos, Agusti ;
Mascarenas, Jose L. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (36) :13020-13030
[5]  
[Anonymous], 2010, ANGEW CHEM, DOI [10.1002/ange.200905000., DOI 10.1002/ANGE.200905000]
[6]   Pd(II) acts simultaneously as a Lewis acid and as a transition-metal catalyst: Synthesis of cyclic alkenyl ethers from acetylenic aldehydes [J].
Asao, N ;
Nogami, T ;
Takahashi, K ;
Yamamoto, Y .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (05) :764-765
[7]   Transition Metal Catalyzed Cycloisomerizations of 1,n-Allenynes and -Allenenes [J].
Aubert, Corinne ;
Fensterbank, Louis ;
Garcia, Pierre ;
Malacria, Max ;
Simonneau, Antoine .
CHEMICAL REVIEWS, 2011, 111 (03) :1954-1993
[8]   Enantioselective IrI-Catalyzed Carbocyclization of 1,6-Enynes by the Chiral Counterion Strategy [J].
Barbazanges, Marion ;
Auge, Mylene ;
Moussa, Jamal ;
Amouri, Hani ;
Aubert, Corinne ;
Desmarets, Christophe ;
Fensterbank, Louis ;
Gandon, Vincent ;
Malacria, Max ;
Ollivier, Cyril .
CHEMISTRY-A EUROPEAN JOURNAL, 2011, 17 (49) :13789-13794
[9]   Synthesis and Catalytic Activity of Gold Chiral Nitrogen Acyclic Carbenes and Gold Hydrogen Bonded Heterocyclic Carbenes in Cyclopropanation of Vinyl Arenes and in Intramolecular Hydroalkoxylation of Allenes [J].
Bartolome, Camino ;
Garcia-Cuadrado, Domingo ;
Ramiro, Zoraida ;
Espinet, Pablo .
INORGANIC CHEMISTRY, 2010, 49 (21) :9758-9764
[10]   Exploring the Scope of Nitrogen Acyclic Carbenes (NACs) in Gold-Catalyzed Reactions [J].
Bartolome, Camino ;
Garcia-Cuadrado, Domingo ;
Ramiro, Zoraida ;
Espinet, Pablo .
ORGANOMETALLICS, 2010, 29 (16) :3589-3592