Mechanical properties of 3-glycidoxypropyltrimethoxysilane functionalized multi-walled carbon nanotubes/epoxy composites cured by electron beam irradiation

被引:6
作者
Lu, Yanyan [1 ]
Li, Hua [1 ]
Lin, Mingjiang [2 ]
Ng, Weihua [2 ]
Liu, Hezhou [1 ]
机构
[1] Shanghai Jiao Tong Univ, Sch Mat Sci & Engn, State Key Lab Met Matrix Composites, Shanghai 200240, Peoples R China
[2] Temasek Polytech, Temasek Appl Sci Sch, Singapore, Singapore
基金
美国国家科学基金会;
关键词
Composites; carbon nanotubes; electron beam curing; epoxy; chemical modification; EPOXY NANOCOMPOSITES; CATIONIC-POLYMERIZATION; TRIBOLOGICAL PROPERTIES; REINFORCEMENT; SURFACE; MORPHOLOGY; DISPERSION; SILICA; MATRIX; RESINS;
D O I
10.1177/0021998312450927
中图分类号
TB33 [复合材料];
学科分类号
摘要
Electron beam (EB) curing is a high rate manufacturing technique for preparing of the epoxy composites. In this study, EB radiation was used to prepare carbon nanotubes (CNTs)/epoxy composites and the effects of 3-glycidoxypropyltrimethoxysilane (GPTMS) functionalized multi-walled carbon nanotubes (MWNTs) on the mechanical properties of EB cured MWNTs/epoxy composites were studied given the important effects on the composites performance of interfacial adhesion between the CNTs and epoxy. The results showed that a substantial increase of the Vicker's hardness appeared at MWNTs content of 0.1wt%, but further filler content increase led to insignificant changes. Also the tensile modulus of the 0.25wt% GPTMS functionalized MWNTs (GPTMS-MWNTs)/epoxy composites was enhanced by 34.9%. Dynamic mechanical analysis studies revealed that filling the 0.25wt% GPTMS-MWNTs into epoxy can produce an 18.4? (from 121.1? to 139.5?) increase in T-g as well. It was concluded that GPTMS functionalization has a significant effect on the mechanical properties of MWNTs/epoxy composites.
引用
收藏
页码:1685 / 1694
页数:10
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