Effect of compositional variations on phase transition and electric field-induced strain of (Pb, Ba) (Nb, Zr, Sn, Ti)O3 ceramics

被引:14
作者
Zhang, Qingfeng [1 ]
Zhang, Yangyang [2 ]
Yang, Tongqing [1 ]
Jiang, Shenglin [3 ]
Wang, Jinfei [1 ]
Chen, Shengchen [1 ]
Li, Gang [1 ]
Yao, Xi [1 ]
机构
[1] Tongji Univ, Funct Mat Res Lab, Shanghai 200092, Peoples R China
[2] Huanghe Sci & Technol Coll, Inst Informat Engn, Zhengzhou 450000, Peoples R China
[3] Huazhong Univ Sci & Technol, Dept Elect Sci & Technol, Wuhan 430074, Peoples R China
基金
中国国家自然科学基金; 中国博士后科学基金;
关键词
Actuators; Antiferroelectric ceramic; Electric field-induced strain; Phase transition; DIELECTRIC-PROPERTIES; ZIRCONATE-TITANATE; ADDITIONS; BARIUM;
D O I
10.1016/j.ceramint.2012.12.047
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
(Pb0.97Ba0.02)Nb-0.02(Zr0.55Sn0.45-xTix)(0.98)O-3 (PBNZST, 0.03 <= x <= 0.06) ceramics were prepared by conventional solid state synthesis and their crystal structure, ferroelectric, dielectric, and electric field-induced strain properties were systemically investigated. A transformation from antiferroelectric (AFE) phase to ferroelectric (FE) phase was observed at 0.05 < x < 0.06. Besides, with the increase of Ti content, the electric field-induced strain decreased, due to the larger strain of APE ceramics compared to FE ceramics. Further, when the measuring frequency decreased, the strain improved, because the electric field at low frequency allows a more efficient switching of domains, resulting in larger strain. The maximum strain of 0.55% was obtained in (Pb0.97Ba0.02)Nb-0.02(Zr0.55Sn0.45-xTix)(0.98)O-3 antiferroelectric ceramics with x=0.03 at 2 Hz. (C) 2012 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
引用
收藏
页码:5403 / 5406
页数:4
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