Crofton weed derived activated carbon by microwave-induced KOH activation and application to wastewater treatment

被引:26
作者
Cheng, Song [1 ,2 ,3 ,4 ]
Zhang, Libo [1 ,2 ,3 ,4 ]
Xia, Hongying [1 ,2 ,3 ,4 ]
Zhang, Shengzhou [1 ,2 ,3 ,4 ]
Peng, Jinhui [1 ,2 ,3 ,4 ]
Wang, Shixing [1 ,2 ,3 ,4 ]
机构
[1] Kunming Univ Sci & Technol, State Key Lab Complex Nonferrous Met Resources Cl, Kunming 650093, Yunnan, Peoples R China
[2] Kunming Univ Sci & Technol, Yunnan Prov Key Lab Intensificat Met, Kunming 650093, Yunnan, Peoples R China
[3] Natl Local Joint Lab Engn Applicat Microwave Ener, Kunming 650093, Yunnan, Peoples R China
[4] Kunming Univ Sci & Technol, Fac Met & Energy Engn, Kunming 650093, Yunnan, Peoples R China
关键词
Crofton weed; Activated carbon; Microwave heating; Adsorption; Wastewater treatment; LOW-COST ADSORBENT; CHEMICAL ACTIVATION; ASSISTED PREPARATION; ADSORPTION; REMOVAL; MECHANISMS; KINETICS; FIBERS; LEAVES; SHELL;
D O I
10.1007/s10934-016-0221-0
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Crofton weed, a kind of global exotic weeds, was utilized as materials for the preparation of activated carbon via microwave-induced KOH activation. The key parameters that characterize the activated carbon such as the BET surface area and total pore volume were estimated to be 3918 m(2)/g and 2.383 mL/g, respectively. The physico-chemical properties of activated carbon were characterized by FTIR, XRD, SEM and TEM. In addition, the activated carbon was exposed to methylene blue, which was used to model the migration of organic pollutants in the wastewater adsorption and to assess liquid phase adsorption properties. The equilibrium adsorption data showed that the adsorption behavior followed the Langmuir isotherm with the highest adsorption capacity of 387.60 mg/g. Pseudo-second order kinetic model was found to adequately describe the adsorption process. Thermodynamic calculations showed that the adsorption was a spontaneous and endothermic process, as well as a physisorption process.
引用
收藏
页码:1597 / 1607
页数:11
相关论文
共 48 条
[1]   Microporous activated carbon from Siris seed pods by microwave-induced KOH activation for metronidazole adsorption [J].
Ahmed, Muthanna J. ;
Theydan, Samar K. .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2013, 99 :101-109
[2]   Ultrafiltration technology with a ceramic membrane for reactive dye removal: Optimization of membrane performance [J].
Alventosa-deLara, E. ;
Barredo-Damas, S. ;
Alcaina-Miranda, M. I. ;
Iborra-Clar, M. I. .
JOURNAL OF HAZARDOUS MATERIALS, 2012, 209 :492-500
[3]  
Anbia M, 2015, INT J ENVIRON RES, V9, P649
[4]   Thermodynamics and kinetics of adsorption of Cu(II) from aqueous solutions onto a new cation exchanger derived from tamarind fruit shell [J].
Anirudhan, T. S. ;
Radhakrishnan, P. G. .
JOURNAL OF CHEMICAL THERMODYNAMICS, 2008, 40 (04) :702-709
[5]   Chitosan-clay composite as highly effective and low-cost adsorbent for batch and fixed-bed adsorption of methylene blue [J].
Auta, M. ;
Hameed, B. H. .
CHEMICAL ENGINEERING JOURNAL, 2014, 237 :352-361
[6]   Optimized waste tea activated carbon for adsorption of Methylene Blue and Acid Blue 29 dyes using response surface methodology [J].
Auta, M. ;
Hameed, B. H. .
CHEMICAL ENGINEERING JOURNAL, 2011, 175 :233-243
[7]   Preparation of waste tea activated carbon using potassium acetate as an activating agent for adsorption of Acid Blue 25 dye [J].
Auta, M. ;
Hameed, B. H. .
CHEMICAL ENGINEERING JOURNAL, 2011, 171 (02) :502-509
[8]   Structure, surface morphology and electrochemical properties of brominated activated carbons [J].
Barpanda, Prabeer ;
Fanchini, Giovanni ;
Amatucci, Glenn G. .
CARBON, 2011, 49 (07) :2538-2548
[9]   Preparation of high specific surface area activated carbon from walnut shells by microwave-induced KOH activation [J].
Cheng, Song ;
Zhang, Libo ;
Xia, Hongying ;
Peng, Jinhui ;
Zhang, Shengzhou ;
Wang, Shixing .
JOURNAL OF POROUS MATERIALS, 2015, 22 (06) :1527-1537
[10]   Production of activated carbon from bamboo scaffolding waste-process design, evaluation and sensitivity analysis [J].
Choy, KKH ;
Barford, JP ;
McKay, G .
CHEMICAL ENGINEERING JOURNAL, 2005, 109 (1-3) :147-165