Activated carbon coated with polyaniline as an electrode material in supercapacitors

被引:88
|
作者
Wang Qin [1 ]
Li Jian-ling [1 ]
Gao Fei [1 ]
Li Wen-sheng [2 ]
Wu Ke-zhong [1 ]
Wang Xin-dong [1 ]
机构
[1] Univ Sci & Technol Beijing, Dept Phys Chem, Beijing 100083, Peoples R China
[2] Jinzhou Kaimei Energy Co Ltd, Jinzhou 121000, Peoples R China
关键词
supercapacitor; polyaniline; activated carbon; cyclic voltammetry; specific capacitance;
D O I
10.1016/S1872-5805(08)60030-X
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The performance of activated carbons coated with polyaniline (PANI-C) by polymerization of aniline Using cyclic voltammetry was investigated as an electrode for supercapacitors by scanning electron microscopy, electrochemical impedance spectroscopy, and constant current charge/discharge measurement. Results showed that a PANT thin film was uniformly deposited on the surface of the activated carbon, forming an interlinked porous network. The PANI-C composite electrodes had better cycling stability than PANT electrodes and the specific capacitance of the composite electrodes was 587 F/g, which was much higher than that of the pristine activated carbon (140 F/g), owing to the faradic reaction of PANT with the electrolyte. The PANT electrode was less stable than the PANI-C composite electrode with a capacitance decay from 513 to 334 F/g for the former and 415 to 385 for the latter, after 50 cycles.
引用
收藏
页码:275 / 280
页数:6
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