In Situ STM Investigation of Two-Dimensional Chiral Assemblies through Schiff-Base Condensation at a Liquid/Solid Interface

被引：44

作者：

Hu, Fang-Yun ^{[1
,2
]}

Zhang, Xue-Mei ^{[1
]}

Wang, Xiao-Chen ^{[3
]}

Wang, Shuai ^{[1
]}

Wang, Hai-Qiao ^{[3
]}

Duan, Wu-Biao ^{[2
]}

Zeng, Qing-Dao ^{[1
]}

Wang, Chen ^{[1
]}

机构：

[1] Natl Ctr Nanosci & Technol NCNST, Beijing 100190, Peoples R China

[2] Beijing Jiaotong Univ, Sch Sci, Dept Chem, Beijing 100044, Peoples R China

[3] Beijing Univ Chem Technol, State Key Lab Organ Inorgan Composites, Coll Mat Sci & Engn, Beijing 100029, Peoples R China

来源：

ACS APPLIED MATERIALS & INTERFACES | 2013年 / 5卷 / 05期

基金：

中国国家自然科学基金;

关键词：

chirality; self-assembly; STM; nanoflower; Schiff-base reaction; two-dimensional; SCANNING-TUNNELING-MICROSCOPY; SUPRAMOLECULAR NETWORK; MOLECULAR NETWORKS; PHOTO-REGULATION; SURFACE; NANOSTRUCTURES; TRANSFORMATION; RECOGNITION; TRANSITION; MONOLAYER;

D O I：

10.1021/am303236w

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Nanoscaled two-dimensional (2D) chiral architectures are increasingly receiving scientific interest, because of their potential applications in many domains. In this paper, we present a new method for constructing 2D chiral architectures on surface. Based on in situ Schiff-base reaction of achiral dialdehyde with two types of achiral amines at the solid/liquid interface, two chiral species have been directly formed and confirmed by means of a scanning tunneling microscopy (STM) technique. This work introduces a novel strategy to construct 2D surface chirality, which might be applied in fabricating functional films and nanoelectronic devices.

引用

页码：1583 / 1587

页数：5

共 40 条

[11] Nucleoside-Assisted Self-Assembly of Oligo(p-phenylenevinylene)s at Liquid/Solid Interface: Chirality and Nanostructures [J].

Guo, Zongxia ;

De Cat, Inge ;

Van Averbeke, Bernard ;

Lin, Jianbin ;

Wang, Guojie ;

Xu, Hong ;

Lazzaroni, Roberto ;

Beljonne, David ;

Meijer, E. W. ;

Schenning, Albertus P. H. J. ;

De Feyter, Steven .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (44) :17764-17771

[12] Halogen bonds as stabilizing interactions in a chiral self-assembled molecular monolayer [J].

Gutzler, Rico ;

Ivasenko, Oleksandr ;

Fu, Chaoying ;

Brusso, Jaclyn L. ;

Rosei, Federico ;

Perepichka, Dmitrii F. .

CHEMICAL COMMUNICATIONS, 2011, 47 (33) :9453-9455

[13] Chiral selection on inorganic crystalline surfaces [J].

Hazen, RM ;

Sholl, DS .

NATURE MATERIALS, 2003, 2 (06) :367-374

[14] Effects of alkyl chain length, solvent and tandem Claisen rearrangement on two-dimensional structures of noncyclic isobutenyl compounds: scanning tunnelling microscopic study [J].

Kikkawa, Yoshihiro ;

Omori, Kazuhiro ;

Takahashi, Mayuko ;

Kanesato, Masatoshi ;

Hiratani, Kazuhisa .

ORGANIC & BIOMOLECULAR CHEMISTRY, 2012, 10 (40) :8087-8094

[15] Self-Assembled Trimer Structures Highlight the Competitive Roles of Intermolecular and Adsorbate-Substrate Interactions: PVBA Trimer on Pd(111) [J].

Kim, Byung I. ;

Kim, Soomin .

LANGMUIR, 2012, 28 (21) :8010-8016

[16] Chiral recognition in dimerization of adsorbed cysteine observed by scanning tunnelling microscopy [J].

Kühnle, A ;

Linderoth, TR ;

Hammer, B ;

Besenbacher, F .

NATURE, 2002, 415 (6874) :891-893

[17] Molecular symmetry breaking and chiral expression of discotic liquid crystals in two-dimensional systems [J].

Li, CJ ;

Zeng, QD ;

Wu, P ;

Xu, SL ;

Wang, C ;

Qiao, YH ;

Wan, LJ ;

Bai, CL .

JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (51) :13262-13267

[18] Transformation of Self-Assembled Structure by the Addition of Active Reactant [J].

Li, Yibao ;

Wan, Junhua ;

Deng, Ke ;

Han, Xiaona ;

Lei, Shengbin ;

Yang, Yanlian ;

Zheng, Qiyu ;

Zeng, Qingdao ;

Wang, Chen .

JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (14) :6540-6544

[19] Chiral Hierarchical Molecular Nanostructures on Two-Dimensional Surface by Controllable Trinary Self-Assembly [J].

Liu, Jia ;

Chen, Ting ;

Deng, Xin ;

Wang, Dong ;

Pei, Jian ;

Wan, Li-Jun .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (51) :21010-21015

[20] Exploring the Complexity of Supramolecular Interactions for Patterning at the Liquid-Solid Interface [J].

Mali, Kunal S. ;

Adisoejoso, Jinne ;

Ghijsens, Elke ;

De Cat, Inge ;

De Feyter, Steven .

ACCOUNTS OF CHEMICAL RESEARCH, 2012, 45 (08) :1309-1320

← 1 2 3 4 →