Giant Rugby Ball [{CpBnFe(η5-P5)}24Cu96Br96] Derived from, Pentaphosphaferrocene and CuBr2

被引：68
作者：
Heindl, Claudia [1 ]
Peresypkina, Eugenia V. [2 ,3 ]
Virovets, Alexander V. [2 ,3 ]
Kremer, Werner [4 ]
Scheer, Manfred [1 ]
机构：
[1] Univ Regensburg, Inst Inorgan Chem, D-93040 Regensburg, Germany
[2] RAS Acad, Siberian Div, Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia
[3] Novosibirsk State Univ, Novosibirsk 630090, Russia
[4] Univ Regensburg, Inst Biophys & Phys Biochem, D-93040 Regensburg, Germany
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2015年 / 137卷 / 34期
基金：
欧洲研究理事会;
关键词：
CHALCOGENIDE CLUSTERS; MOLECULES; SIZE; CHEMISTRY; ALUMINUM; CORE;
D O I：
10.1021/jacs.5b06835
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The self-assembly of [(CpFe)-Fe-Bn(eta(5)-P-5)] (cp(Bn) = eta(5)-C-5(CH2Ph)(5)) with CuBr2 leads to the formation of an unprecedented rugby ball-shaped supra-molecule consisting of 24 units of the pentaphosphaferrocene and an extended CuBr framework, which does not follow the fullerene topology. The resulting scaffold of 312 noncarbon atoms reveals three different coordination modes of the cyclo-P-5 ligand including a novel pi-coordination. The outer dimensions of 3.7 x 4.6 nm of the sphere approach the range of the size of proteins. With a value of 32.1 nm(3), it is 62 times larger in volume than a C-60 molecule. Surprisingly, this giant rugby ball is also slightly soluble in CH2Cl2.
引用
收藏
页码：10938 / 10941
页数：4
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