Giant Rugby Ball [{CpBnFe(η5-P5)}24Cu96Br96] Derived from, Pentaphosphaferrocene and CuBr2

被引：68

作者：

Heindl, Claudia ^{[1
]}

Peresypkina, Eugenia V. ^{[2
,3
]}

Virovets, Alexander V. ^{[2
,3
]}

Kremer, Werner ^{[4
]}

Scheer, Manfred ^{[1
]}

机构：

[1] Univ Regensburg, Inst Inorgan Chem, D-93040 Regensburg, Germany

[2] RAS Acad, Siberian Div, Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia

[3] Novosibirsk State Univ, Novosibirsk 630090, Russia

[4] Univ Regensburg, Inst Biophys & Phys Biochem, D-93040 Regensburg, Germany

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2015年 / 137卷 / 34期

基金：

欧洲研究理事会;

关键词：

CHALCOGENIDE CLUSTERS; MOLECULES; SIZE; CHEMISTRY; ALUMINUM; CORE;

D O I：

10.1021/jacs.5b06835

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The self-assembly of [(CpFe)-Fe-Bn(eta(5)-P-5)] (cp(Bn) = eta(5)-C-5(CH2Ph)(5)) with CuBr2 leads to the formation of an unprecedented rugby ball-shaped supra-molecule consisting of 24 units of the pentaphosphaferrocene and an extended CuBr framework, which does not follow the fullerene topology. The resulting scaffold of 312 noncarbon atoms reveals three different coordination modes of the cyclo-P-5 ligand including a novel pi-coordination. The outer dimensions of 3.7 x 4.6 nm of the sphere approach the range of the size of proteins. With a value of 32.1 nm(3), it is 62 times larger in volume than a C-60 molecule. Surprisingly, this giant rugby ball is also slightly soluble in CH2Cl2.

引用

页码：10938 / 10941

页数：4

共 45 条

[1] Synthesis and crystal structures of the ligand-stabilized over chalcogenide clusters [Ag154Se77(dppxy)18], [Ag320(StBu)60S130(dppp)12], [Ag352S128(StC5H11)96], and [Ag490S188(StC5H11)114]
Anson, Christopher E.
Eichhofer, Andreas
Issac, Ibrahim
Fenske, Dieter
Fuhr, Olaf
Sevillano, Paloma
Persau, Claudia
Stalke, Dietmar
Zhang, Jiatao
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (07) : 1326 - 1331
[2] Assembly of the First Fullerene-Type Metal-Organic Frameworks Using a Planar Five-Fold Coordination Node
Bacsa, John
Less, Robert J.
Skelton, Helen E.
Soracevic, Zlatko
Steiner, Alexander
Wilson, Thomas C.
Wood, Paul T.
Wright, Dominic S.
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (36) : 8279 - 8282
[3] Synthesis of inorganic fullerene-like molecules
Bai, JF
Virovets, AV
Scheer, M
[J]. SCIENCE, 2003, 300 (5620) : 781 - 783
[4] Ferrocene and Pentaphosphaferrocene: A Comparative Study Regarding Redox Chemistry
Butovskiy, Mikhail V.
Balazs, Gabor
Bodensteiner, Michael
Peresypkina, Eugenia V.
Virovets, Alexander V.
Sutter, Joerg
Scheer, Manfred
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (10) : 2972 - 2976
[5] Metal Chalcogenide Clusters on the Border between Molecules and Materials
Corrigan, John F.
Fuhr, Olaf
Fenske, Dieter
[J]. ADVANCED MATERIALS, 2009, 21 (18) : 1867 - 1871
[6] Tunable Porosities and Shapes of Fullerene-Like Spheres
Dielmann, Fabian
Fleischmann, Matthias
Heindl, Claudia
Peresypkina, Eugenia V.
Virovets, Alexander V.
Gschwind, Ruth M.
Scheer, Manfred
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2015, 21 (16) : 6208 - 6214
[7] A Nano-sized Supramolecule Beyond the Fullerene Topology
Dielmann, Fabian
Heindl, Claudia
Hastreiter, Florian
Peresypkina, Eugenia V.
Virovets, Alexander V.
Gschwind, Ruth M.
Scheer, Manfred
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (49) : 13605 - 13608
[8] Coordination Polymers Based on [Cp*Fe(η5-P5)]: Solid-State Structure and MAS NMR Studies
Dielmann, Fabian
Schindler, Andrea
Scheuermayer, Sabine
Bai, Junfeng
Merkle, Roger
Zabel, Manfred
Virovets, Alexander V.
Peresypkina, Eugenia V.
Brunklaus, Gunther
Eckert, Hellmut
Scheer, Manfred
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2012, 18 (04) : 1168 - 1179
[9] New Pentaphosphaferrocenes
Dielmann, Fabian
Merkle, Roger
Heinl, Sebastian
Scheer, Manfred
[J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2009, 64 (01): : 3 - 10
[10] Dresselhaus M. S., 1996, Science of fullerenes and carbon nanotubes: their properties and applications

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