The microstructure and optical properties of p-type microcrystalline silicon thin films characterized by ex-situ spectroscopic ellipsometry

被引:8
作者
Zhang, He [1 ]
Zhang, Xiaodan [1 ]
Hou, Guofu [1 ]
Wei, Changchun [1 ]
Sun, Jian [1 ]
Geng, Xinhua [1 ]
Xiong, Shaozhen [1 ]
Zhao, Ying [1 ]
机构
[1] Nankai Univ, Inst Photoelect Thin Film Devices & Tech, Tianjin 300071, Peoples R China
关键词
Spectroscopic ellipsometry; Microcrystalline silicon; Crystalline volume fraction; Gas doping; Optical function; SOLAR-CELLS; CRYSTALLINE; GROWTH;
D O I
10.1016/j.tsf.2012.03.081
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Ex-situ spectroscopy ellipsometry (SE) was applied on the similar to 25 nm thick p-type hydrogenated microcrystalline silicon (p-mu c-Si:H) thin films deposited by very high frequency plasma enhanced chemical vapor deposition. Several optical models were built and compared with each other for ex-situ SE data analysis considering both the oxide surface and the heterogeneous bulk condition to reveal the material microstructure and obtain optical function. The SE results imply that the p-mu c-Si:H has both an oxide rich surface and the bulk with a flexible amorphous phase, the bandgap of which depends on the gas doping ratio (DR) of B2H6/SiH4. At the same time, we were able to distinguish p-mu c-Si:H materials in crystalline volume fraction by ex-situ SE as confirmed by Raman scattering. In this way, we showed the effect of DR on mu c-Si:H thin films in microstructural and optical properties. (c) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:17 / 21
页数:5
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