High-pressure compressibility and phase stability of Mn-dolomite (kutnohorite)

被引:4
|
作者
Palaich, Sarah E. M. [1 ]
Heffern, Robert A. [1 ]
Watenphul, Anke [1 ]
Knight, Jason [2 ]
Kavner, Abby [1 ]
机构
[1] Univ Calif Los Angeles, Dept Earth Planetary & Space Sci, Los Angeles, CA 90095 USA
[2] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Adv Light Source, Berkeley, CA 94720 USA
关键词
Carbonate; high-pressure; X-ray diffraction; dolomite; compressibility;
D O I
10.2138/am-2015-5095
中图分类号
P3 [地球物理学]; P59 [地球化学];
学科分类号
0708 ; 070902 ;
摘要
We measured the bulk modulus and phase stability of a natural Mn-dolomite, kutnohorite, to 19 GPa. At room temperature, kutnohorite is stable in the rhombohedral dolomite phase up to 19 GPa, with an isothermal bulk modulus of 85(6) GPa (K' = 4). The compressibility of kutnohorite is found to match well with both single and double carbonate trends with respect to bulk modulus and unit-cell volume. The thermoelastic properties measured in this study show that the Mn dolomite end-member fits well with the systematic of all the rhombohedral carbonates, both calcite (single carbonate) and dolomite (double carbonate) type.
引用
收藏
页码:2242 / 2245
页数:4
相关论文
共 50 条
  • [1] Ab initio study of the dolomite to dolomite-II high-pressure phase transition
    Zucchini, Azzurra
    Prencipe, Mauro
    Belmonte, Donato
    Comodi, Paola
    EUROPEAN JOURNAL OF MINERALOGY, 2017, 29 (02) : 227 - 238
  • [2] High-pressure compressibility and thermal expansion of aragonite
    Palaich, Sarah E. M.
    Heffern, Robert A.
    Hanfland, Michael
    Lausi, Andrea
    Kavner, Abby
    Manning, Craig E.
    Merlini, Marco
    AMERICAN MINERALOGIST, 2016, 101 (7-8) : 1651 - 1658
  • [3] Effects of hydrostaticity and Mn-substitution on dolomite stability at high pressure
    Wang, Faxiang
    Zhao, Chaoshuai
    Xu, Liangxu
    Liu, Jin
    AMERICAN MINERALOGIST, 2022, 107 (12) : 2234 - 2241
  • [4] High-pressure compressibility and vibrational properties of (Ca,Mn)CO3
    Liu, Jin
    Caracas, Razvan
    Fan, Dawei
    Bobocioiu, Ema
    Zhang, Dongzhou
    Mao, Wendy L.
    AMERICAN MINERALOGIST, 2016, 101 (12) : 2723 - 2730
  • [5] High-pressure, high-temperature phase stability of iron-poor dolomite and the structures of dolomite-IIIc and dolomite-V
    Binck, Jannes
    Chariton, Stella
    Stekiel, Michal
    Bayarjargal, Lkhamsuren
    Morgenroth, Wolfgang
    Milman, Victor
    Dubrovinsky, Leonid
    Winkler, Bjoern
    PHYSICS OF THE EARTH AND PLANETARY INTERIORS, 2020, 299
  • [6] COMPRESSIBILITY OF TUGTUPITE AT HIGH-PRESSURE
    WERNER, S
    PLECH, A
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1995, 210 (06): : 418 - 420
  • [7] The stability and compressibility of MgAl2O4 high-pressure polymorphs
    S. Ono
    T. Kikegawa
    Y. Ohishi
    Physics and Chemistry of Minerals, 2006, 33 : 200 - 206
  • [8] The stability and compressibility of MgAl2O4 high-pressure polymorphs
    Ono, S
    Kikegawa, T
    Ohishi, Y
    PHYSICS AND CHEMISTRY OF MINERALS, 2006, 33 (03) : 200 - 206
  • [9] High-pressure behavior of sillimanite and kyanite: compressibility, decomposition and indications of a new high-pressure phase
    Friedrich, A
    Kunz, M
    Winkler, B
    Le Bihan, T
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 2004, 219 (06): : 324 - 329
  • [10] The effect of cation ordering and temperature on the high-pressure behaviour of dolomite
    Zucchini, Azzurra
    Comodi, Paola
    Nazzareni, Sabrina
    Hanfland, Michael
    PHYSICS AND CHEMISTRY OF MINERALS, 2014, 41 (10) : 783 - 793