Lignin oxidation by MnO2 under the irradiation of blue light

被引：37

作者：

Dai, Jinhuo ^{[1
]}

Patti, Antonio F. ^{[1
]}

Styles, Gavin N. ^{[1
]}

Nanayakkara, Sepa ^{[1
]}

Spiccia, Leone ^{[1
]}

Arena, Francesco ^{[2
]}

Italiano, Cristina ^{[3
]}

Saito, Kei ^{[1
]}

机构：

[1] Monash Univ, Sch Chem, Wellington Rd, Clayton, Vic 3800, Australia

[2] Univ Messina, Dipartimento Ingn Elettron Chim & Ingn Ind, I-98166 Messina, Italy

[3] CNR, Inst Adv Technol Energy Nicola Giordano, Via Salita S Lucia 5, I-98126 Messina, Italy

来源：

GREEN CHEMISTRY | 2019年 / 21卷 / 08期

关键词：

OCTAHEDRAL MOLECULAR-SIEVES; PHOTOCATALYTIC DEGRADATION; MANGANESE-DIOXIDE; AEROBIC OXIDATION; WATER OXIDATION; BENZYL ALCOHOL; IONIC LIQUID; DEPOLYMERIZATION; CONVERSION; CATALYST;

D O I：

10.1039/c8gc03498b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Traditionally, conventional heat has been required for a large proportion of the oxidation and degradation process to utilise lignin from biomass. A photocatalysis system which is considered as a novel and green strategy for chemical reactions has been applied and a photo-MnO2 catalytic lignin oxidation method has been developed. In this study, we investigated a promising photocatalytic heterogeneous system for lignin oxidation. Recyclable MnO2 which is readily available and blue light which is a hazardless light are used in this system. 1-Phenylethanol was used as a model compound to study the suitable conditions for this system. After optimizing the reaction conditions, organosolv lignin, kraft lignin, and alkali lignin were applied to this system and the successful oxidation of lignins and their further degradation were shown.

引用

页码：2005 / 2014

页数：10

共 57 条

[1] Nanostructured MnOx catalysts in the liquid phase selective oxidation of benzyl alcohol, with oxygen: Part I. Effects of Ce and Fe addition on structure and reactivity [J].

Arena, Francesco ;

Gumina, Bianca ;

Lombardo, Agata F. ;

Espro, Claudia ;

Patti, Antonio ;

Spadaro, Lorenzo ;

Spiccia, Leone .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2015, 162 :260-267

[2]

Azadi P., 2012, RENEW SUST ENERG REV, V21, P506

[3] Liquid fuels, hydrogen and chemicals from lignin: A critical review [J].

Azadi, Pooya ;

Inderwildi, Oliver R. ;

Farnood, Ramin ;

King, David A. .

RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2013, 21 :506-523

[4] A new ionic liquid: 2-hydroxy ethylammonium formate [J].

Bicak, N .

JOURNAL OF MOLECULAR LIQUIDS, 2005, 116 (01) :15-18

[5] New rare earth hafnium oxynitride perovskites with photocatalytic activity in water oxidation and reduction [J].

Black, Ashley P. ;

Suzuki, Hajime ;

Higashi, Masanobu ;

Frontera, Carlos ;

Ritter, Clemens ;

De, Chandan ;

Sundaresan, A. ;

Abe, Ryu ;

Fuertes, Amparo .

CHEMICAL COMMUNICATIONS, 2018, 54 (12) :1525-1528

[6] Characterisation of structure-dependent functional properties of lignin with infrared spectroscopy [J].

Boeriu, CG ;

Bravo, D ;

Gosselink, RJA ;

van Dam, JEG .

INDUSTRIAL CROPS AND PRODUCTS, 2004, 20 (02) :205-218

[7] Redox Catalysis Facilitates Lignin Depolymerization [J].

Bosque, Irene ;

Magallanes, Gabriel ;

Rigoulet, Mathilde ;

Karkas, Markus D. ;

Stephenson, Corey R. J. .

ACS CENTRAL SCIENCE, 2017, 3 (06) :621-628

[8] Catalytic Systems for Water Splitting [J].

Brudvig, Gary W. ;

Reek, Joost N. H. ;

Sakai, Ken ;

Spiccia, Leone ;

Sun, Licheng .

CHEMPLUSCHEM, 2016, 81 (10) :1017-1019

[9] HIGHLY EFFICIENT HETEROGENEOUS PHOTOOXIDATION OF 2-PROPANOL TO ACETONE WITH AMORPHOUS MANGANESE OXIDE CATALYSTS [J].

CAO, H ;

SUIB, SL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (12) :5334-5342

[10] Review of current and future softwood kraft lignin process chemistry [J].

Chakar, FS ;

Ragauskas, AJ .

INDUSTRIAL CROPS AND PRODUCTS, 2004, 20 (02) :131-141

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