All polymer photovoltaics: From small inverted devices to large roll-to-roll coated and printed solar cells

被引：82

作者：

Liu, Yao ^{[1
,2
]}

Larsen-Olsen, Thue T. ^{[2
]}

Zhao, Xingang ^{[1
]}

Andreasen, Birgitta ^{[2
]}

Sondergaard, Roar R. ^{[2
]}

Helgesen, Martin ^{[2
]}

Norrman, Kion ^{[2
]}

Jorgensen, Mikkel ^{[2
]}

Krebs, Frederik C. ^{[2
]}

Zhan, Xiaowei ^{[1
,3
]}

机构：

[1] Chinese Acad Sci, Inst Chem, CAS Key Lab Organ Solids, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China

[2] Tech Univ Denmark, Dept Energy Convers & Storage, DK-4000 Roskilde, Denmark

[3] Peking Univ, Coll Engn, Dept Mat Sci & Engn, Beijing 100871, Peoples R China

来源：

SOLAR ENERGY MATERIALS AND SOLAR CELLS | 2013年 / 112卷

基金：

新加坡国家研究基金会;

关键词：

All-polymer solar cells; Inverted geometry; Roll-to-roll process; CONJUGATED POLYMER; TANDEM POLYMER; ORGANIC PHOTOVOLTAICS; ELECTRON-TRANSPORT; PERFORMANCE; ACCEPTOR; COPOLYMER; DONOR; BENZODITHIOPHENE; LAYER;

D O I：

10.1016/j.solmat.2013.01.025

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

Inverted all polymer solar cells based on a blend of a perylene diimide based polymer acceptor and a dithienosilole based polymer donor were fabricated from small area devices to roll-to-roll (R2R) coated and printed large area modules. The device performance was successfully optimized by using solvent additive to tune the phase separation. By adding 2% chloronaphthalene as solvent additive for small area (0.25 cm(2)) devices, a power conversion efficiency (PCE) up to 0.63% was achieved for inverted geometry, higher than that (0.39%) of conventional geometry. This polymer blend showed excellent solution processibility and R2R coated and printed large area (4.2 cm(2)) solar cells exhibited a PCE of 0.20%. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：157 / 162

页数：6

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