Crystal structure of monoprotonated cobalt(II) nitrilotriacetate tetrahydrate Co(HNta)•4H2O

被引：4
|
作者：
Polyakova, IN
Poznyak, AL
Egorova, OA
机构：
[1] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 117907, Russia
[2] Belarussian Acad Sci, Inst Atom & Mol Phys, Minsk 220072, BELARUS
[3] Patrice Lumumba Peoples Friendship Univ, Moscow 117198, Russia
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2001年 / 27卷 / 12期
关键词：
Physical Chemistry; 4H2O; Crystallization; Crystal Structure; Cobalt;
D O I：
10.1023/A:1013061028537
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
X-ray diffraction analysis of Co(HNta). 4H(2)O (I) (H(3)Nta = N(CH2COOH)(3)) revealed that its crystals are isostructural to a Zn analog and built from [Co(HNta)(H2O)(3)] complex molecules and crystallization water. The octahedral coordination of the Co atom includes two O atoms and an N atom provided by the chelating tridentate HNta(2-) ligand (average Co-O (Nta) 2.055 Angstrom and Co-N 2.205 Angstrom) and three O atoms of water molecules on the shared face (average Co-O(w) 2.105 Angstrom).
引用
收藏
页码：852 / 854
页数：3
相关论文
共 50 条
  • [1] Crystal Structure of Monoprotonated Cobalt(II) Nitrilotriacetate Tetrahydrate Co(HNta) · 4H2O
    I. N. Polyakova
    A. L. Poznyak
    O. A. Egorova
    Russian Journal of Coordination Chemistry, 2001, 27 : 852 - 854
  • [2] Crystal structure of monoprotonated cobalt(II) nitrilotriacetate tetrahydrate, Co(HNta)·4H2O
    Polyakova, I.N.
    Poznyak, A.L.
    Egorova, O.A.
    2001, Maik Nauka (27): : 904 - 907
  • [3] Crystal structure of monoprotonated Ni(II) nitrilotriacetate tetrahydrate
    Petrenko, PA
    Gdaniec, M
    Simonov, YA
    Stavila, VG
    Gulea, AP
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2004, 30 (11) : 813 - 817
  • [4] Crystal Structure of Monoprotonated Ni(II) Nitrilotriacetate Tetrahydrate
    P. A. Petrenko
    M. Gdaniec
    Yu. A. Simonov
    V. G. Stavila
    A. P. Gulea
    Russian Journal of Coordination Chemistry, 2004, 30 : 813 - 817
  • [5] CRYSTALLINE-STRUCTURE OF ZINC ZNHNTA.4H2O MONOPROTONATED NITRILOTRIACETATE TETRAHYDRATE
    GLADKIKH, OP
    POLYNOVA, TN
    PORAIKOSHITS, MA
    MITROFANOVA, ND
    KOORDINATSIONNAYA KHIMIYA, 1990, 16 (06): : 758 - 763
  • [6] Crystal structure of calcium [aqua(nitrilotriacetatocobaltate(II)] tetrahydrate, Ca[Co(Nta)(H2O)]2 • 4H2O
    Zasurskaya, LA
    Polyakova, IN
    Polynova, TN
    Poznyak, AL
    Sergienko, VS
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2001, 27 (04) : 270 - 274
  • [7] Crystal Structure of Calcium [Aqua(Nitrilotriacetatocobaltate(II)] Tetrahydrate, Ca[Co(Nta)(H2O)]2· 4H2O
    L. A. Zasurskaya
    I. N. Polyakova
    T. N. Polynova
    A. L. Poznyak
    V. S. Sergienko
    Russian Journal of Coordination Chemistry, 2001, 27 : 270 - 274
  • [8] CRYSTAL-STRUCTURE OF MONOADIPATO TETRAAQUO COBALT(II), CO(C6H8O4), 4H2O
    GUPTA, MP
    SINHA, SK
    INDIAN JOURNAL OF PHYSICS AND PROCEEDINGS OF THE INDIAN ASSOCIATION FOR THE CULTIVATION OF SCIENCE-PART A, 1979, 53 (04): : 471 - &
  • [9] Crystal structure of calcium dithiocyanate tetrahydrate, Ca(NCS)2 • 4H2O
    Held, P
    Bohaty, L
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2001, 216 (03): : 337 - 337
  • [10] Crystal structure of strontium aqua(ethylenediaminetetraacetato)cobaltate(II) tetrahydrate Sr[CoEdta(H2O)]·4H2O
    2001, MAIK Nauka (46):
12345