Synthesis and Energetic Properties of 4,4′,5,5′-Tetranitro-2,2′-biimidazolate(N4BIM) Salts

被引：21

作者：

Chavez, David E. ^{[1
]}

Parrish, Damon ^{[2
]}

Preston, Daniel N. ^{[1
]}

Mares, Isaac W. ^{[1
]}

机构：

[1] Los Alamos Natl Lab, Weap Experimentat Div, Los Alamos, NM 87545 USA

[2] USN, Res Lab, Washington, DC 20375 USA

来源：

PROPELLANTS EXPLOSIVES PYROTECHNICS | 2012年 / 37卷 / 06期

关键词：

Propellants; Explosives; NITROGEN; DECOMPOSITION; COMPOUND; CHAIN;

D O I：

10.1002/prep.201200040

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

This paper describes the synthesis and characterization of several salts of 4,4',5,5'-tetranitro-2,2'-biimidazolate (N4BIM). Each of the salts were characterized chemically, thermally, morphologically, as well as with respect to destructive stimuli (impact, electrostatic discharge, friction, thermal). These salts show promise as propellant ingredient additives, and in particular, the bis-triaminoguanidinium salt of N4BIM displays excellent burn rate and combustion behavior. Our combustion studies have shown that TAGN4BIM displays a fast burning rate and has the lowest pressure dependence exponent yet measured for a triaminoguanidinium salt.

引用

页码：647 / 652

页数：6

共 50 条

[31] An energetic derivative of 2,2′,4,4′,6,6′-hexanitrostilbene (HNS) and its DMF solvate crystallized from HNS solution with tertiary amine additives
Cao, Xiong
Guan, Yuxiang
Yang, Liyuan
Yan, Mi
Ma, Qin
Fan, Guijuan
Liu, Yu
Huang, Shiliang
JOURNAL OF ENERGETIC MATERIALS, 2019, 37 (01) : 90 - 97
[32] Synthesis, Crystal Structure and Magnetic Properties of a Porous Manganese Coordination Polymer with N-[4-Carboxyphenyl)-sulfonyl]glycine and 4,4′-dipyridyl
Wang, Yong-Wei
Ma, Lu-Fang
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2012, 42 (07) : 1009 - 1012
[33] Multipurpose [1,2,4]triazolo[4,3-b][1,2,4,5] tetrazine-based energetic materials
Liu, Yingle
Zhao, Gang
Tang, Yongxing
Zhang, Jichuan
Hu, Lu
Imler, Gregory H.
Parrish, Damon A.
Shreeve, Jean'ne M.
JOURNAL OF MATERIALS CHEMISTRY A, 2019, 7 (13) : 7875 - 7884
[34] Synthesis and properties of energetic salts based on 3-nitro-5-nitroimino-1,2,4-oxadiazole
Gao, Yong-Tao
Zhao, Lin-Man
Pang, Fu-Qing
Qi, Xiu-Juan
Huang, Jing-Lun
Chen, Fu-Xue
CHINESE CHEMICAL LETTERS, 2016, 27 (03) : 433 - 436
[35] Synthesis and properties of energetic salts based on 3-nitro-5-nitroimino-1,2,4-oxadiazole
Yong-Tao Gao
Lin-Man Zhao
Fu-Qing Pang
Xiu-Juan Qi
Jing-Lun Huang
Fu-Xue Chen
ChineseChemicalLetters, 2016, 27 (03) : 433 - 436
[36] 2,2′,4,4′-Tetrabromodiphenyl ether injures cell viability and mitochondrial function of mouse spermatocytes by decreasing mitochondrial proteins Atp5b and Uqcrc1
Huang, Shaoping
Wang, Jing
Cui, Yiqiang
ENVIRONMENTAL TOXICOLOGY AND PHARMACOLOGY, 2016, 46 : 301 - 310
[37] Synthesis and Characterization of the Nitrophenol Energetic Ionic Salts of 5,6,7,8-Tetrahydrotetrazolo[1,5-b][1,2,4]triazine
Wu, Jin-Ting
Zhang, Jian-Guo
Yin, Xin
He, Piao
Zhang, Tong-Lai
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2014, (27) : 4690 - 4695
[38] Hydrazinium lanthanide oxalates: synthesis, structure and thermal reactivity of N2H5[Ln2(C2O4)4(N2H5)]•4H2O, Ln = Ce, Nd
De Almeida, Lucie
Grandjean, Stephane
Rivenet, Murielle
Patisson, Fabrice
Abraham, Francis
DALTON TRANSACTIONS, 2014, 43 (12) : 4680 - 4688
[39] Synthesis and characterization of novel polyimides derived from 4,4′-bis(5-amino-2-pyridinoxy)benzophenone: effect of pyridine and ketone units in the main
Wang, Chunbo
Zhao, Xiaogang
Tian, Dongbo
Wang, Daming
Chen, Chunhai
Zhou, Hongwei
DESIGNED MONOMERS AND POLYMERS, 2017, 20 : 97 - 105
[40] Research on the thermal behavior of novel heat resistance explosive 5,5′-bis (2,4,6-trinitropheny1)-2,2′-bi(1,3,4-oxadiazole)
Zhou, Jing
Ding, Li
Bi, Fuqiang
Wang, Bozhou
Zhang, Junlin
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2018, 129 : 189 - 194

← 1 2 3 4 5 →