Synthesis and Energetic Properties of 4,4′,5,5′-Tetranitro-2,2′-biimidazolate(N4BIM) Salts

被引：21
|
作者：
Chavez, David E. [1 ]
Parrish, Damon [2 ]
Preston, Daniel N. [1 ]
Mares, Isaac W. [1 ]
机构：
[1] Los Alamos Natl Lab, Weap Experimentat Div, Los Alamos, NM 87545 USA
[2] USN, Res Lab, Washington, DC 20375 USA
来源：
PROPELLANTS EXPLOSIVES PYROTECHNICS | 2012年 / 37卷 / 06期
关键词：
Propellants; Explosives; NITROGEN; DECOMPOSITION; COMPOUND; CHAIN;
D O I：
10.1002/prep.201200040
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
This paper describes the synthesis and characterization of several salts of 4,4',5,5'-tetranitro-2,2'-biimidazolate (N4BIM). Each of the salts were characterized chemically, thermally, morphologically, as well as with respect to destructive stimuli (impact, electrostatic discharge, friction, thermal). These salts show promise as propellant ingredient additives, and in particular, the bis-triaminoguanidinium salt of N4BIM displays excellent burn rate and combustion behavior. Our combustion studies have shown that TAGN4BIM displays a fast burning rate and has the lowest pressure dependence exponent yet measured for a triaminoguanidinium salt.
引用
收藏
页码：647 / 652
页数：6
相关论文
共 50 条
  • [1] Combustion Properties of Amino-Substituted Guanidinium 4,4′,5,5′-Tetranitro-2,2′-biimidazolate(N4BIM) Salts
    Tappan, Bryce C.
    Chavez, David E.
    PROPELLANTS EXPLOSIVES PYROTECHNICS, 2015, 40 (01) : 13 - 15
  • [2] Energetic double salts based on 4,4′,5,5′-tetranitro-2,2′-biimidazolate
    Liu, Long
    Sun, Peng
    Zhang, Yanqiang
    Du, Fang
    Pang, Aimin
    JOURNAL OF MOLECULAR STRUCTURE, 2020, 1208 (1208)
  • [3] Bishydrazinium and Diammonium Salts of 4,4′,5,5′-Tetranitro-2,2′-biimidazolate (TNBI): Synthesis and Properties
    Paraskos, Alexander J.
    Cooke, Edward D.
    Caflin, Kelley C.
    PROPELLANTS EXPLOSIVES PYROTECHNICS, 2015, 40 (01) : 46 - 49
  • [4] Heterocyclic Energetic Salts of 4,4′,5,5′-Tetranitro-2,2′-Biimidazole
    Liu, Long
    Zhang, Yanqiang
    Zhang, Suojiang
    Fei, Teng
    JOURNAL OF ENERGETIC MATERIALS, 2015, 33 (03) : 202 - 214
  • [5] High Nitrogen Energetic Salts of 4,4′,5,5′-Tetranitro-2,2′-Biimidazole
    Kim, Seung Hee
    Kim, Jin Seuk
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2013, 34 (08) : 2503 - 2506
  • [6] Synthesis and properties of N-amino derivatives based on 4,4',5,5'-tetranitro-2,2'-biimidazole
    Li Y.-N.
    Chen T.
    Hu J.-J.
    Chang P.
    Wang B.
    Zhang H.-W.
    Wang B.-Z.
    Gao Xiao Hua Xue Gong Cheng Xue Bao/Journal of Chemical Engineering of Chinese Universities, 2021, 35 (02): : 331 - 335
  • [7] STRUCTURE OF 4,4',5,5'-TETRANITRO-2,2'-BIIMIDAZOLE DIHYDRATE
    CROMER, DT
    STORM, CB
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1990, 46 : 1957 - 1958
  • [8] Explosive Properties of 4,4′,5,5′-Tetranitro-2,2′-bi-1H-imidazole Dihydrate
    Lewczuk, Rafal
    Szala, Mateusz
    Recko, Judyta
    Cudzilo, Stanislaw
    Klapoetke, Thomas M.
    Trzcinski, Waldemar A.
    Szymanczyk, Leszek
    CENTRAL EUROPEAN JOURNAL OF ENERGETIC MATERIALS, 2016, 13 (03): : 612 - 626
  • [9] Synthesis and characterization of 4,4′,5,5′-tetranitro-2,2′-bi-1H-imidazole (TNBI)
    Cho, SG
    Cho, JR
    Goh, EM
    Kim, JK
    Damavarapu, R
    Surapaneni, R
    PROPELLANTS EXPLOSIVES PYROTECHNICS, 2005, 30 (06) : 445 - 449
  • [10] Nucleophilic Reactions of The Bis Ammonium Salt of 4,4′,5,5′-Tetranitro-2,2′-biimidazole
    Breiner, Megan M.
    Chavez, David E.
    Parrish, Damon A.
    SYNLETT, 2013, 24 (04) : 519 - 521
12345