Palladium-catalyzed 1,2-addition of potassium aryl- and alkenyltrifluoroborates to aldehydes using thioether-imidazolinium carbene ligands

被引：40

作者：

Kuriyama, Masami ^{[1
]}

Shimazawa, Rumiko ^{[1
]}

Enomoto, Terumichi ^{[1
]}

Shirai, Ryuichi ^{[1
]}

机构：

[1] Doshisha Womens Coll Liberal Arts, Fac Pharmaceut Sci, Kyoto 6100395, Japan

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2008年 / 73卷 / 17期

基金：

日本学术振兴会;

关键词：

D O I：

10.1021/jo801352h

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Palladium-catalyzed 1,2-addition of potassium aryl- and alkenyltrifluoroborates to aldehydes using thioether-imidazolinium carbene ligands proceeded readily under aqueous conditions. This process tolerated a diverse range of potassium trifluoroborate salts and aldehydes, giving a variety of carbinol derivatives with good to excellent yields.

引用

页码：6939 / 6942

页数：4

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