Oxygen and chlorine evolution on RuO2+TiO2+CeO2+Nb2O5 mixed oxide electrodes

被引：90

作者：

Santana, MHP ^{[1
]}

De Faria, LA ^{[1
]}

机构：

[1] UFU, Inst Quim, BR-38400902 Uberlandia, MG, Brazil

来源：

ELECTROCHIMICA ACTA | 2006年 / 51卷 / 17期

关键词：

Ru plus Ti plus Cc plus Nb oxides; oxygen evolution; chlorine evolution; ruthenium oxide; electrocatalysis;

D O I：

10.1016/j.electacta.2005.09.050

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

A systematic investigation was conducted on the mechanism and electrocatalytic properties Of 02 and Cl, evolution on mixed oxide electrodes of nominal composition: Ti/[Ru(0.3)Ti(0.6)CC(0.1-x)1]O-2[Nb2O5]((x)) (0 <= x <= 0. 1). For the oxygen evolution, a 30 mV Tafel slope is obtained in the presence of CeO2, while in its absence a 40 mV coefficient is observed. The intrinsic electrocatalytic activity is mainly due to electronic factors, as result of the synergism between Ru and Cc oxides. For chlorine evolution, the Tafel slope (30 mV) is independent on oxide composition. The best global electrocatalytic activity for CIER was observed in the absence of Nb2O5 additive. Variation of the voltammetric charge throughout the experiments confirms high CeO2 content compositions are fragile, due mainly to the porosity caused by CeO2 presence. On the other hand, Nb2O5 addition decreases considerably this instability. (c) 2005 Elsevier Ltd. All rights reserved.

引用

页码：3578 / 3585

页数：8

共 41 条

[1] KINETICS AND MECHANISM OF OXYGEN EVOLUTION ON IRO2-BASED ELECTRODES CONTAINING TI AND CE ACIDIC SOLUTIONS [J].