Synthesis, structural characterization and optical properties of new compounds: Centrosymmetric Ba2GaMQ5 (M=Sb,Bi; Q=Se,Te), Ba2InSbTe5 and noncentrosymmetric Ba2InSbSe5

被引：28
|
作者：
Hao, Wenyu [1 ,2 ,3 ]
Mei, Dajiang [1 ,2 ,3 ]
Yin, Wenlong [1 ,2 ,3 ]
Feng, Kai [1 ,2 ,3 ]
Yao, Jiyong [1 ,2 ]
Wu, Yicheng [1 ,2 ]
机构：
[1] Chinese Acad Sci, Tech Inst Phys & Chem, Ctr Crystal Res & Dev, Beijing 100190, Peoples R China
[2] Chinese Acad Sci, Tech Inst Phys & Chem, Key Lab Funct Crystals & Laser Technol, Beijing 100190, Peoples R China
[3] Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 2013年 / 198卷
基金：
中国国家自然科学基金;
关键词：
Selenides; Tellurides; Synthesis; Crystal structure; SHG; BISMUTH SULFIDES; THERMOELECTRIC PROPERTIES; CRYSTAL; GE; SI; SERIES; LAYER; EARTH; SE; SN;
D O I：
10.1016/j.jssc.2012.09.034
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The six compounds Ba(2)GaMQ(5) (M=Sb,Bi; Q=Se,Te) and Ba(2)InSbQ(5) (Q=Se,Te) have been synthesized for the first time. Ba(2)GaMQ(5) (M=Sb,Bi; Q=Se,Te) and Ba2InSbTe5 crystallize in the centrosymmetric space group Pnma, while Ba2InSbSe5 belongs to the noncentrosymmetric polar space group Cmc2(1). The structures of the six new compounds contain infinite (1)(infinity)[MM'Q(5)](4-) anionic chains built by MQ(4) (M'=Ga,In) tetrahedra and heavily distorted M'Q(6) (M'=Sb,Bi) octahedra. Ba2InSbSe5 possesses a band gap of 1.92(5) eV and exhibits a weak powder second harmonic generation signal using the 2090 nm laser as fundamental wavelength. (C) 2012 Elsevier Inc. All rights reserved.
引用
收藏
页码：81 / 86
页数：6
相关论文
共 39 条
  • [31] Synthesis and optical properties of intense blue colors oxides based on Mn5+ in tetrahedral sites in Ba7Al2-xMnxO10+y
    Wang, Yuqian
    Lei, Honghong
    Jiang, Peng
    Liu, Lin
    Cui, Kunyang
    Cao, Wenbin
    CERAMICS INTERNATIONAL, 2021, 47 (01) : 686 - 691
  • [32] New Vanadium Selenites: Centrosymmetric Ca2(VO2)2(SeO3)3(H2O)2, Sr2(VO2)2(SeO3)3, and Ba(V2O5)(SeO3), and Noncentrosymmetric and Polar A4(VO2)2(SeO3)4(Se2O5) (A = Sr2+ or Pb2+)
    Yeon, Jeongho
    Kim, Sang-Hwan
    Sau Doan Nguyen
    Lee, Hana
    Halasyamani, P. Shiv
    INORGANIC CHEMISTRY, 2012, 51 (01) : 609 - 619
  • [33] Synthesis, structural, morphology, spectroscopic and optical study of new metal orthophosphate MII(Ga0.5Sb0.5)(PO4)2 (MII= Sr, Pb, Ba) compounds
    Fakhreddine, Rachid
    Ouasri, Ali
    Aatiq, Abderrahim
    JOURNAL OF SOLID STATE CHEMISTRY, 2024, 329
  • [34] Linear and nonlinear optical properties of trigonal borate crystals K7MIn2-xYbx(B5O10)3 (M = Ca, Sr, Ba; x=0 ... 2) with isolated B5O10 units ...
    Jamous, A. Y.
    Svetlichnyi, V. A.
    Kuznetsov, A. B.
    Kokh, K. A.
    Kononova, N. G.
    Lapin, I. N.
    Bolatov, A.
    Zholdas, Y. A.
    Kokh, A. E.
    JOURNAL OF ALLOYS AND COMPOUNDS, 2023, 935
  • [35] Studies on linear heterotrimetallic M-E-M (M=Mo, W; E=Hg, Zn) compounds - Synthesis, properties and structural characterization of [eta(5)-RC(5)H(4)(CO)(3)M](2)Zn (M=Mo, W; R=CO(2)Me, CO(2)Et)
    Song, LC
    Dong, YB
    Tao, ZF
    Hu, QM
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 1996, 17 (12): : 1878 - 1881
  • [36] Influence of the counterions on the structures of ternary Zn/Sn/Se anions:: Synthesis and properties of [Rb10(H2O)14.5][Zn4(μ4-Se)2(SnSe4)4] and [Ba5(H2O)32][Zn5Sn(μ3-Se)4(SnSe4)4]
    Ruzin, E
    Dehnen, S
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2006, 632 (05): : 749 - 755
  • [37] Quaternary Pnictides with Complex, Noncentrosymmetric Structures. Synthesis and Structural Characterization of the New Zintl Phases Na11Ca2Al3Sb8, Na4CaGaSb3, and Na15Ca3In5Sb12
    Wang, Yi
    Stoyko, Stanislav
    Bobev, Svilen
    INORGANIC CHEMISTRY, 2015, 54 (04) : 1931 - 1939
  • [38] Structural, magnetic, electronic, optical and mechanical properties of actinide perovskite oxides XAnO 3 [X = Cs + , Ba 2+; An = Np 5+, Np 4+ ]: GGA, GGA plus U and GGA plus U plus mBJ investigations
    Saad, M. Musa H-E
    Alsobhi, B. O.
    JOURNAL OF MOLECULAR GRAPHICS & MODELLING, 2024, 131
  • [39] Synthesis, crystal structure, and spectrum properties of a new borate Ba4K2Zn5(B3O6)3(B9O19) with two isolated types of blocks: 3[3Δ] and 3 [2Δ,+1T]+3Δ+3[2Δ+1T]
    Chen, Xuean
    Chen, Yanjun
    Wu, Long
    Chang, Xinan
    Xiao, Weigiang
    SOLID STATE SCIENCES, 2014, 27 : 47 - 54
1234