Di-ortho-beryllated Carbodiphosphorane: A Compound with a Metal Carbon Double Bond to an Element of the s-Block

被引：46

作者：

Buchner, Magnus R. ^{[3
]}

Pan, Sudip ^{[1
]}

Poggel, Christina ^{[2
]}

Spang, Nils ^{[3
]}

Mueller, Matthias ^{[3
]}

Frenking, Gernot ^{[1
]}

Sundermeyer, Joerg ^{[2
]}

机构：

[1] Philipps Univ Marburg, Fachbereich Chem, Theoret Chem, D-35032 Marburg, Germany

[2] Philipps Univ Marburg, Fachbereich Chem, Anorgan Chem, D-35032 Marburg, Germany

[3] Philipps Univ Marburg, Fachbereich Chem, Anorgan Chem, Nachwuchsgrp Berylliumchem, D-35032 Marburg, Germany

来源：

ORGANOMETALLICS | 2020年 / 39卷 / 17期

关键词：

STRUCTURAL-CHARACTERIZATION; NATURAL ORBITALS; CARBENE COMPLEX; CALCIUM CARBENE; COVALENT RADII; BASIS-SETS; DENSITY; CHEMISTRY; REACTIVITY; ENERGY;

D O I：

10.1021/acs.organomet.0c00434

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Double bonds have been realized fora wide variety of lements in the p -, d-, and f-blocks. However, no s-block metal complexes with a don hie bond have been identified. Here we report the synthesis and characterization of a di-ortho-beryllated carbodiphosphorane, which exhibits a double dative Be = C bond. This species shows an unprecedented bonding situation at the metal center, which was extensively analyzed by experimental and comPutational means

引用

页码：3224 / 3231

页数：8

共 82 条

[21] Frenking G, 2014, CHEMICAL BOND: FUNDAMENTAL ASPECTS OF CHEMICAL BONDING, P121
[22] Frisch M. J., 2009, GAUSSIAN 09 REVISION
[23] Fürstner A, 2000, ANGEW CHEM INT EDIT, V39, P3012
[24] Glendening E. D., 2018, NBO 70
[25] The first carbene complex of a diorganoberyllium:: Synthesis and structural characterization of Ph2Be(i-Pr-carbene) and Ph2Be(n-Bu2O)
Gottfriedsen, Jochen
Blaurock, Steffen
[J]. ORGANOMETALLICS, 2006, 25 (15) : 3784 - 3786
[26] GRIMME S, 2010, J CHEM PHYS, V132, DOI DOI 10.1063/1.3382344
[27] Alkaline earths as main group reagents in molecular catalysis
Hill, Michael S.
Liptrot, David J.
Weetman, Catherine
[J]. CHEMICAL SOCIETY REVIEWS, 2016, 45 (04) : 972 - 988
[28] ShelXle: a Qt graphical user interface for SHELXL
Huebschle, Christian B.
Sheldrick, George M.
Dittrich, Birger
[J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2011, 44 : 1281 - 1284
[29] Synthesis, Structure, and Reactivity of a Dihydrido Borenium Cation
Ines, Blanca
Patil, Mahendra
Carreras, Javier
Goddard, Richard
Thiel, Walter
Alcarazo, Manuel
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (36) : 8400 - 8403
[30] Dative and Electron-Sharing Bonding in Transition Metal Compounds
Jerabek, Paul
Schwerdtfeger, Peter
Frenking, Gernot
[J]. JOURNAL OF COMPUTATIONAL CHEMISTRY, 2019, 40 (01) : 247 - 264

← 1 2 3 4 5 6 7 8 9 →