One-step hydrothermal synthesis of MnO2/graphene composite for electrochemical energy storage

被引:45
|
作者
Zhang, Qian [1 ]
Wu, Xiangfang [1 ]
Zhang, Qingqing [1 ]
Yang, Fengjian [1 ]
Dong, Hongzhou [1 ]
Sui, Jing [1 ]
Dong, Lifeng [1 ,2 ]
机构
[1] Qingdao Univ Sci & Technol, Coll Mat Sci & Engn, Qingdao 266042, Shandong, Peoples R China
[2] Hamline Univ, Dept Phys, St Paul, MN 55104 USA
基金
中国国家自然科学基金;
关键词
MnO2/rGO; Solvothermal; Composite; Electrochemical properties; REDUCED GRAPHENE OXIDE; BINDER-FREE ELECTRODE; SUPERCAPACITOR ELECTRODE; FACILE SYNTHESIS; PERFORMANCE; MNO2; NANOCOMPOSITES; NANOSHEETS; NANOTUBES; SHEETS;
D O I
10.1016/j.jelechem.2019.02.031
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
In this paper, MnO2/reduced graphene oxide (rGO) composite is prepared by one-step hydrothermal method. With anchoring MnO2 nanosheets on the surface of rGO, the extraordinary structure provides MnO2/rGO composite with large specific surface area and numerous channels for rapid diffusion of electrolyte ions, electron transport and high conductivity due to the presence of rGO. Electrochemical results demonstrate that MnO2/rGO composite has good capacitive performance with a specific capacitance of 255 F.g(-1) at a current density of 0.5 A.g(-1), a retention rate of 84.5% after 10,000 cycles at 10 A.g(-1), and an energy density of 33.33 Wh.kg(-1) with a power density of 20,000 W.kg(-1). The results above indicate that MnO2/rGO composite has potential applications for supercapacitor electrode materials.
引用
收藏
页码:108 / 115
页数:8
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