Circular dichroism and circularly polarized luminescence triggered by self-assembly of tris(phenylisoxazolyl) benzenes possessing a perylenebisimide moiety

被引:100
作者
Ikeda, Toshiaki [1 ]
Masuda, Tetsuya [1 ]
Hirao, Takehiro [1 ]
Yuasa, Junpei [2 ]
Tsumatori, Hiroyuki [2 ]
Kawai, Tsuyoshi [2 ]
Haino, Takeharu [1 ]
机构
[1] Hiroshima Univ, Grad Sch Sci, Dept Chem, 1-3-1 Kagamiyama, Higashihiroshima 7398526, Japan
[2] Nara Inst Sci & Technol, Grad Sch Mat Sci, Nara 6300192, Japan
关键词
COOPERATIVE SUPRAMOLECULAR POLYMERIZATION; NUCLEATION-ELONGATION; BISIMIDE DYES; LIGHT; FILMS; COMPLEXES; MOLECULES; MECHANISM; CHIRALITY; HELICENE;
D O I
10.1039/c2cc31512b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Chiral tris(phenylisoxazolyl) benzenes possessing a perylenebisimide moiety assembled to form helical stacks. The self-assembling behavior of the helical stacks responded to changes in solvent properties, temperature, and concentration. Strong circular dichroism (CD) and circularly polarized luminescence (CPL) of their assemblies were displayed, and were controlled by external stimuli.
引用
收藏
页码:6025 / 6027
页数:3
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