Assembly of functionalized α-hydroxy carbonyl compounds via combination of N-heterocyclic carbene and Pd catalysts

被引：18

作者：

He, Jinmei ^{[1
]}

Tang, Shibing ^{[1
]}

Tang, Shouchu ^{[1
]}

Liu, Jian ^{[1
]}

Sun, Yongquan ^{[1
]}

Pan, Xinfu ^{[1
]}

She, Xuegong ^{[1
,2
]}

机构：

[1] Lanzhou Univ, State Key Lab Appl Organ Chem, Dept Chem, Lanzhou 730000, Peoples R China

[2] Lanzhou Univ, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China

来源：

TETRAHEDRON LETTERS | 2009年 / 50卷 / 04期

关键词：

N-heterocyclic carbenes; Benzoin condensations; pi-Allylpalladium; Allylic alkylation; Multicomponent reactions; INTRAMOLECULAR STETTER REACTION; DIELS-ALDER REACTIONS; GAMMA-BUTYROLACTONES; MULTICOMPONENT REACTIONS; NUCLEOPHILIC CARBENES; ALPHA; BETA-UNSATURATED ALDEHYDES; BENZOIN CONDENSATION; EFFICIENT SYNTHESIS; CONJUGATE UMPOLUNG; DIRECT ANNULATIONS;

D O I：

10.1016/j.tetlet.2008.11.032

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Functionalized a-hydroxy carbonyl compounds were prepared from various aldehydes and allylic acetates via a multicomponent reaction, which were catalyzed by N-heterocyclic carbene and Pd catalysts in one pot. (c) 2008 Elsevier Ltd. All rights reserved.

引用

页码：430 / 433

页数：4

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