NO2 sensing performance of SnO2 hollow-sphere sensor

被引：176

作者：

Zhang, Jun ^{[1
]}

Wang, Shurong ^{[1
]}

Wang, Yanmei ^{[1
]}

Wang, Yan ^{[1
]}

Zhu, Baolin ^{[1
]}

Xia, Huijuan ^{[1
]}

Guo, Xianzhi ^{[1
]}

Zhang, Shoumin ^{[1
]}

Huang, Weiping ^{[1
]}

Wu, Shihua ^{[1
]}

机构：

[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China

来源：

SENSORS AND ACTUATORS B-CHEMICAL | 2009年 / 135卷 / 02期

基金：

中国国家自然科学基金;

关键词：

SnO2 hollow sphere; Sensor; NO2; Response; Selectivity; SEMICONDUCTING OXIDE NANOBELTS; MESOPOROUS TIN OXIDE; GAS SENSORS; NANOCRYSTALLINE SNO2; LOW-TEMPERATURE; SOLUTION-PHASE; PARTICLE-SIZE; LARGE-SCALE; MICROSPHERES; NANORODS;

D O I：

10.1016/j.snb.2008.09.026

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

This work examined the possibility of using SnO2 hollow spheres mediated by carbon microspheres for the efficient detection of NO2 gas. The influences of gas concentration. operating temperature. crystallite (grain) size and structure feature on the sensing performance of the sensors based on SnO2 hollow spheres were comprehensively studied. The SnO2 hollow spheres had a mean crystallite size of 12.7, 14.1 and 22.8 nm when calcined at 450, 500 and 550 degrees C, respectively. It was found that the SnO2 hollow spheres calcined at 450 degrees C with a crystallite size of 12.7 nm were the most sensitive to NO2 gas. The sensor also had a better selectivity to NO2 than to ethanol, methanol, gasoline, acetone, CCl4 and NH3 when operated at 160 degrees C. (c) 2008 Elsevier B.V. All rights reserved.

引用

页码：610 / 617

页数：8

共 53 条

[1] Field-effect transistors based on single semiconducting oxide nanobelts [J].

Arnold, MS ;

Avouris, P ;

Pan, ZW ;

Wang, ZL .

JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (03) :659-663

[2] Conduction model of metal oxide gas sensors [J].

Barsan, N ;

Weimar, U .

JOURNAL OF ELECTROCERAMICS, 2001, 7 (03) :143-167

[3] Preparation of mesoporous tin oxide for electrochemical applications [J].

Chen, FL ;

Liu, ML .

CHEMICAL COMMUNICATIONS, 1999, (18) :1829-1830

[4] Large-scale, solution-phase growth of single-crystalline SnO2 nanorods [J].

Cheng, B ;

Russell, JM ;

Shi, WS ;

Zhang, L ;

Samulski, ET .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (19) :5972-5973

[5] Hydrothermal synthesis of SnO2 nanoparticles and their gas-sensing of alcohol [J].

Chiu, Hui-Chi ;

Yeh, Chen-Sheng .

JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (20) :7256-7259

[6] Stable and highly sensitive gas sensors based on semiconducting oxide nanobelts [J].

Comini, E ;

Faglia, G ;

Sberveglieri, G ;

Pan, ZW ;

Wang, ZL .

APPLIED PHYSICS LETTERS, 2002, 81 (10) :1869-1871

[7] Single crystal SnO2 zigzag nanobelts [J].

Duan, JH ;

Yang, SG ;

Liu, HW ;

Gong, JF ;

Huang, HB ;

Zhao, XN ;

Zhang, R ;

Du, YW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (17) :6180-6181

[8] Simple synthesis of hollow tin dioxide microspheres and their application to lithium-ion battery anodes [J].

Han, SJ ;

Jang, BC ;

Kim, T ;

Oh, SM ;

Hyeon, T .

ADVANCED FUNCTIONAL MATERIALS, 2005, 15 (11) :1845-1850

[9] A review of traffic-related air pollution exposure assessment studies in the developing world [J].

Han, XL ;

Naeher, LP .

ENVIRONMENT INTERNATIONAL, 2006, 32 (01) :106-120

[10]

HEILIG A, 1997, SENSOR ACTUAT B-CHEM, V43, P1

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