A new selective pyrazoline-based fluorescent chemosensor for Cu2+ in aqueous solution

被引:87
作者
Hu, Shengli [1 ]
Zhang, Shushu [1 ]
Hu, Yang [1 ]
Tao, Qing [1 ]
Wu, Anxin [2 ]
机构
[1] Hubei Normal Univ, Dept Chem & Environm Engn, Hubei Key Lab Pollutant Anal & Reuse Technol, Huangshi 435002, Peoples R China
[2] Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Peoples R China
基金
中国国家自然科学基金;
关键词
Pyrazoline; Fluorescent sensor; Copper ion detection; Selective; TRANSITION-METAL IONS; LIVING CELLS; COPPER IONS; DERIVATIVES; SENSOR; MEDIA; PROPERTY; RECEPTOR; CU(II); CATION;
D O I
10.1016/j.dyepig.2012.09.019
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
A new pyrazoline derivate was designed and synthesized. The structure of the pyrazoline was confirmed by single crystal X-ray diffraction and its photophysical properties were studied by absorption and fluorescence spectra. This compound can be used to determine Cu2+ ion with high selectivity and sensitivity among a series of cations in aqueous tetrahydrofuran. This sensor forms a 1:1 complex with Cu2+ and displays fluorescent quenching. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码:509 / 515
页数:7
相关论文
共 50 条
[1]  
[Anonymous], 1990, CHEM J CHINESE U
[2]   A New Selective Chromogenic and Turn-On Fluorogenic Probe for Copper(II) in Water-Acetonitrile 1:1 Solution [J].
Ballesteros, Eduardo ;
Moreno, Daniel ;
Gomez, Teresa ;
Rodriguez, Teresa ;
Rojo, Josefa ;
Garcia-Valverde, Maria ;
Torroba, Tomas .
ORGANIC LETTERS, 2009, 11 (06) :1269-1272
[3]   A SPECTROPHOTOMETRIC INVESTIGATION OF THE INTERACTION OF IODINE WITH AROMATIC HYDROCARBONS [J].
BENESI, HA ;
HILDEBRAND, JH .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1949, 71 (08) :2703-2707
[4]   Synthesis and fluorescent property of some novel bischromophore compounds containing pyrazoline and naphthalimide groups [J].
Bian, Bing ;
Ji, Shun-Jun ;
Shi, Hai-Bin .
DYES AND PIGMENTS, 2008, 76 (02) :348-352
[5]   Synthesis of new 2-(5-substituted-3-phenyl-2-pyrazolinyl)-1, 3-thiazolino[5,4-b]quinoxaline derivatives and evaluation of their antiamoebic activity [J].
Budakoti, Asha ;
Bhat, Abdul Roouf ;
Azam, Amir .
EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY, 2009, 44 (03) :1317-1325
[6]   New fluorescent and colorimetric chemosensors bearing rhodamine and binaphthyl groups for the detection of Cu2+ [J].
Chen, Xiaoqiang ;
Jou, Min Jung ;
Lee, Hanyoung ;
Kou, Songzi ;
Lim, Jeesun ;
Nam, Seong-Won ;
Park, Sungsu ;
Kim, Kwan-Mook ;
Yoon, Juyoung .
SENSORS AND ACTUATORS B-CHEMICAL, 2009, 137 (02) :597-602
[7]  
Crosby G.A., 1971, REV J PHYS CHEM, V75, P991
[8]   Signaling recognition events with fluorescent sensors and switches [J].
de Silva, AP ;
Gunaratne, HQN ;
Gunnlaugsson, T ;
Huxley, AJM ;
McCoy, CP ;
Rademacher, JT ;
Rice, TE .
CHEMICAL REVIEWS, 1997, 97 (05) :1515-1566
[9]   Tuning the photoinduced electron-transfer thermodynamics in 1,3,5-triaryl-2-pyrazoline fluorophores: X-ray structures, photophysical characterization, computational analysis, and in vivo evaluation [J].
Fahrni, CJ ;
Yang, LC ;
VanDerveer, DG .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (13) :3799-3812
[10]   Novel pyrazoline-based selective fluorescent sensor for Zn2+ in aqueous media [J].
Gong, Zhong-Liang ;
Ge, Fei ;
Zhao, Bao-Xiang .
SENSORS AND ACTUATORS B-CHEMICAL, 2011, 159 (01) :148-153