Solid-State NMR Spectroscopy of Metal-Organic Framework Compounds (MOFs)

被引:119
作者
Hoffmann, Herbert C. [1 ]
Debowski, Marta [1 ]
Mueller, Philipp [1 ]
Paasch, Silvia [1 ]
Senkovska, Irena [1 ]
Kaskel, Stefan [1 ]
Brunner, Eike [1 ]
机构
[1] Tech Univ Dresden, Dept Chem & Food Chem, D-01062 Dresden, Germany
关键词
metal-organic frameworks; porous materials; solid-state NMR; host-guest interactions; Xe-129; NMR; DYNAMIC NUCLEAR-POLARIZATION; ANGLE-SPINNING NMR; COORDINATIVELY UNSATURATED SITES; EDGE-SHARING OCTAHEDRA; HIGH-RESOLUTION NMR; X-RAY-DIFFRACTION; XE-129; NMR; MAGNETIC-RESONANCE; CHEMICAL-SHIFT; QUADRUPOLAR NUCLEI;
D O I
10.3390/ma5122537
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Nuclear Magnetic Resonance (NMR) spectroscopy is a well-established method for the investigation of various types of porous materials. During the past decade, metal-organic frameworks have attracted increasing research interest. Solid-state NMR spectroscopy has rapidly evolved into an important tool for the study of the structure, dynamics and flexibility of these materials, as well as for the characterization of host-guest interactions with adsorbed species such as xenon, carbon dioxide, water, and many others. The present review introduces and highlights recent developments in this rapidly growing field.
引用
收藏
页码:2537 / 2572
页数:36
相关论文
共 218 条
  • [1] PRINCIPLES OF DYNAMIC NUCLEAR-POLARIZATION
    ABRAGAM, A
    GOLDMAN, M
    [J]. REPORTS ON PROGRESS IN PHYSICS, 1978, 41 (03) : 395 - 467
  • [2] Controlled modification of the inorganic and organic bricks in an Al-based MOF by direct and post-synthetic synthesis routes
    Ahnfeldt, Tim
    Gunzelmann, Daniel
    Wack, Julia
    Senker, Juergen
    Stock, Norbert
    [J]. CRYSTENGCOMM, 2012, 14 (12): : 4126 - 4136
  • [3] Synthesis and Modification of a Functionalized 3D Open-Framework Structure with MIL-53 Topology
    Ahnfeldt, Tim
    Gunzelmann, Daniel
    Loiseau, Thierry
    Hirsemann, Dunja
    Senker, Juergen
    Ferey, Gerard
    Stock, Norbert
    [J]. INORGANIC CHEMISTRY, 2009, 48 (07) : 3057 - 3064
  • [4] NUCLEAR MAGNETIC RESONANCE SPECTRA FROM A CRYSTAL ROTATED AT HIGH SPEED
    ANDREW, ER
    BRADBURY, A
    EADES, RG
    [J]. NATURE, 1958, 182 (4650) : 1659 - 1659
  • [5] Solid state 17O NMR -: an introduction to the background principles and applications to inorganic materials
    Ashbrook, Sharon E.
    Smith, Mark E.
    [J]. CHEMICAL SOCIETY REVIEWS, 2006, 35 (08) : 718 - 735
  • [6] Solution State NMR Techniques Applied to Solid State Samples: Characterization of Benzoic Acid Confined in MCM-41
    Azais, Thierry
    Hartmeyer, Geoffrey
    Quignard, Sandrine
    Laurent, Guillaume
    Babonneau, Florence
    [J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (19) : 8884 - 8891
  • [7] Solid State NMR Spectroscopy
    Bai, Shi
    Wang, Wei
    Dybowski, Cecil
    [J]. ANALYTICAL CHEMISTRY, 2010, 82 (12) : 4917 - 4924
  • [8] Direct Observation of Molecular-Level Template Action Leading to Self-Assembly of a Porous Framework
    Bajpe, Sneha R.
    Kirschhock, Christine E. A.
    Aerts, Alexander
    Breynaert, Eric
    Absillis, Gregory
    Parac-Vogt, Tatjana N.
    Giebeler, Lars
    Martens, Johan A.
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2010, 16 (13) : 3926 - 3932
  • [9] Strategies for Solid-State NMR Studies of Materials: From Diamagnetic to Paramagnetic Porous Solids
    Bakhmutov, Vladimir I.
    [J]. CHEMICAL REVIEWS, 2011, 111 (02) : 530 - 562
  • [10] Synthesis and Structural Characterization of a 3-D Lithium Based Metal-Organic Framework Showing Dynamic Structural Behavior
    Banerjee, Debasis
    Kim, Sun Jin
    Li, Wei
    Wu, Haohan
    Li, Jing
    Borkowski, Lauren A.
    Philips, Brian L.
    Parise, John B.
    [J]. CRYSTAL GROWTH & DESIGN, 2010, 10 (06) : 2801 - 2805