Solid-State NMR Spectroscopy of Metal-Organic Framework Compounds (MOFs)

被引：121

作者：

Hoffmann, Herbert C. ^{[1
]}

Debowski, Marta ^{[1
]}

Mueller, Philipp ^{[1
]}

Paasch, Silvia ^{[1
]}

Senkovska, Irena ^{[1
]}

Kaskel, Stefan ^{[1
]}

Brunner, Eike ^{[1
]}

机构：

[1] Tech Univ Dresden, Dept Chem & Food Chem, D-01062 Dresden, Germany

来源：

MATERIALS | 2012年 / 5卷 / 12期

关键词：

metal-organic frameworks; porous materials; solid-state NMR; host-guest interactions; Xe-129; NMR; DYNAMIC NUCLEAR-POLARIZATION; ANGLE-SPINNING NMR; COORDINATIVELY UNSATURATED SITES; EDGE-SHARING OCTAHEDRA; HIGH-RESOLUTION NMR; X-RAY-DIFFRACTION; XE-129; NMR; MAGNETIC-RESONANCE; CHEMICAL-SHIFT; QUADRUPOLAR NUCLEI;

D O I：

10.3390/ma5122537

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Nuclear Magnetic Resonance (NMR) spectroscopy is a well-established method for the investigation of various types of porous materials. During the past decade, metal-organic frameworks have attracted increasing research interest. Solid-state NMR spectroscopy has rapidly evolved into an important tool for the study of the structure, dynamics and flexibility of these materials, as well as for the characterization of host-guest interactions with adsorbed species such as xenon, carbon dioxide, water, and many others. The present review introduces and highlights recent developments in this rapidly growing field.

引用

页码：2537 / 2572

页数：36

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