Development of a novel homogeneous and heterogeneous Pd catalytic system for organic transformations

被引:0
作者
Nishimura, T [1 ]
Uemura, S [1 ]
机构
[1] Kyoto Univ, Grad Sch Engn, Dept Energy & Hydrocarbon Chem, Sakyo Ku, Kyoto 6068501, Japan
来源
CATALYSIS SURVEYS FROM JAPAN | 2000年 / 4卷 / 02期
关键词
palladium; oxidation; oxygen; alcohol; alkene; cyclobutanol; cyclobutanone oxime; hydrotalcite; fluorous biphase system;
D O I
暂无
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The results of our new finding on homogeneous and heterogeneous palladium catalytic system for oxidation of alcohols and alkenes using molecular oxygen are described together with several successful attempts to make the system recyclable from the viewpoint of environmental and economical concerns. In addition, some novel organic transformations of tert-cyclobutanols and cyclobutanone oximes are also presented where beta -carbon elimination involving C-C bond fission is a key step.
引用
收藏
页码:135 / 147
页数:13
相关论文
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